Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.jorganchem.2004.09.037
| DC Field | Value | |
|---|---|---|
| dc.title | The photochemical reaction of Os 3(CO) 10(μ-H)(μ- γ-C 5H 3O 2), a triosmium cluster carrying a γ-pyrone ligand, with dimethylacetylenedicarboxylate: Formation of isomeric clusters | |
| dc.contributor.author | Lin, Q. | |
| dc.contributor.author | Leong, W.K. | |
| dc.date.accessioned | 2014-10-16T08:45:34Z | |
| dc.date.available | 2014-10-16T08:45:34Z | |
| dc.date.issued | 2005-01-17 | |
| dc.identifier.citation | Lin, Q., Leong, W.K. (2005-01-17). The photochemical reaction of Os 3(CO) 10(μ-H)(μ- γ-C 5H 3O 2), a triosmium cluster carrying a γ-pyrone ligand, with dimethylacetylenedicarboxylate: Formation of isomeric clusters. Journal of Organometallic Chemistry 690 (2) : 322-327. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2004.09.037 | |
| dc.identifier.issn | 0022328X | |
| dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/95249 | |
| dc.description.abstract | The reaction of the cluster Os 3(CO) 10(μ-H)(μ- γ-C 5H 3O 2) (1), with DMAD under UV irradiation afforded three isomers of the monosubstituted product, Os 3(CO) 9(μ-γ-C 5H 3O 2)(μ 3-MeO 2CCHCCO 2Me) (2), and a disubstituted product, Os 3(CO) 8(μ-γ-C 5H 3O 2)(μ 3-MeO 2CCHCCO 2Me)(μ-MeO 2CCCCO 2Me) (3). The formation of 3 suggests that flipping of the O-heterocycle can occur. © 2004 Elsevier B.V. All rights reserved. | |
| dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2004.09.037 | |
| dc.source | Scopus | |
| dc.subject | Alkyne | |
| dc.subject | Clusters | |
| dc.subject | Osmium | |
| dc.subject | Pyrones | |
| dc.type | Article | |
| dc.contributor.department | CHEMISTRY | |
| dc.description.doi | 10.1016/j.jorganchem.2004.09.037 | |
| dc.description.sourcetitle | Journal of Organometallic Chemistry | |
| dc.description.volume | 690 | |
| dc.description.issue | 2 | |
| dc.description.page | 322-327 | |
| dc.description.coden | JORCA | |
| dc.identifier.isiut | 000226392200011 | |
| Appears in Collections: | Staff Publications | |
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