Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2004.09.037
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dc.titleThe photochemical reaction of Os 3(CO) 10(μ-H)(μ- γ-C 5H 3O 2), a triosmium cluster carrying a γ-pyrone ligand, with dimethylacetylenedicarboxylate: Formation of isomeric clusters
dc.contributor.authorLin, Q.
dc.contributor.authorLeong, W.K.
dc.date.accessioned2014-10-16T08:45:34Z
dc.date.available2014-10-16T08:45:34Z
dc.date.issued2005-01-17
dc.identifier.citationLin, Q., Leong, W.K. (2005-01-17). The photochemical reaction of Os 3(CO) 10(μ-H)(μ- γ-C 5H 3O 2), a triosmium cluster carrying a γ-pyrone ligand, with dimethylacetylenedicarboxylate: Formation of isomeric clusters. Journal of Organometallic Chemistry 690 (2) : 322-327. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2004.09.037
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95249
dc.description.abstractThe reaction of the cluster Os 3(CO) 10(μ-H)(μ- γ-C 5H 3O 2) (1), with DMAD under UV irradiation afforded three isomers of the monosubstituted product, Os 3(CO) 9(μ-γ-C 5H 3O 2)(μ 3-MeO 2CCHCCO 2Me) (2), and a disubstituted product, Os 3(CO) 8(μ-γ-C 5H 3O 2)(μ 3-MeO 2CCHCCO 2Me)(μ-MeO 2CCCCO 2Me) (3). The formation of 3 suggests that flipping of the O-heterocycle can occur. © 2004 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2004.09.037
dc.sourceScopus
dc.subjectAlkyne
dc.subjectClusters
dc.subjectOsmium
dc.subjectPyrones
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2004.09.037
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume690
dc.description.issue2
dc.description.page322-327
dc.description.codenJORCA
dc.identifier.isiut000226392200011
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