Please use this identifier to cite or link to this item:
|Title:||The formation of an enynic-like intermediate in diacetylene binding on Si(100)-2 × 1||Authors:||Huang, H.G.
|Issue Date:||1-Nov-2004||Citation:||Huang, H.G., Lu, X., Xiang, C.L., Teo, T.L., Lai, Y.H., Xu, G.Q. (2004-11-01). The formation of an enynic-like intermediate in diacetylene binding on Si(100)-2 × 1. Chemical Physics Letters 398 (1-3) : 11-14. ScholarBank@NUS Repository. https://doi.org/10.1016/j.cplett.2004.09.034||Abstract:||The covalent attachment of diacetylene (HC≡C-C≡CH) and the formation of a C=C-C≡C structure on Si(100) have been investigated using high-resolution electron energy loss spectroscopy (HREELS) and density functional theory (DFT) calculations. The HREELS spectrum of the chemisorbed monolayer shows the coexistence of ≡Csp-H and =Csp2-H stretching modes coupled with the concurrent observation of the C≡C and C=C stretching modes. The experimental results unambiguously demonstrate a [2 + 2]-like cycloaddition mechanism for diacetylene chemisorption on Si(100) through the binding between one of the C≡C groups and a Si dimer, consistent with the prediction of DFT calculations. © 2004 Elsevier B.V. All rights reserved.||Source Title:||Chemical Physics Letters||URI:||http://scholarbank.nus.edu.sg/handle/10635/95235||ISSN:||00092614||DOI:||10.1016/j.cplett.2004.09.034|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Nov 27, 2022
WEB OF SCIENCETM
checked on Nov 10, 2022
checked on Nov 24, 2022
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.