The first fully characterized 1,3-polyazulene: High electrical conductivity resulting from cation radicals and polycations generated upon protonation

Please use this identifier to cite or link to this item: https://doi.org/10.1021/ol0274615

Title:	The first fully characterized 1,3-polyazulene: High electrical conductivity resulting from cation radicals and polycations generated upon protonation
Authors:	Wang, F. Lai, Y.-H. Kocherginsky, N.M. Kosteski, Y.Y.
Issue Date:	3-Apr-2003
Citation:	Wang, F., Lai, Y.-H., Kocherginsky, N.M., Kosteski, Y.Y. (2003-04-03). The first fully characterized 1,3-polyazulene: High electrical conductivity resulting from cation radicals and polycations generated upon protonation. Organic Letters 5 (7) : 995-998. ScholarBank@NUS Repository. https://doi.org/10.1021/ol0274615
Abstract:	Figure presented 1,3-Polyazulene prepared by the chemical polymerization of 1,3-dibromoazulene with Ni(COD)2 was aptly characterized by spectroscopic analysis. The azulene units remain intact in the isolated polymer. Protonation of 1,3-polyazulene by trifluoroacetic acid was found to exhibit high conductivity and paramagnetic properties via the formation of cation radicals and di- and polycations.
Source Title:	Organic Letters
URI:	http://scholarbank.nus.edu.sg/handle/10635/95232
ISSN:	15237060
DOI:	10.1021/ol0274615
Appears in Collections:	Staff Publications

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