Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/94948

DC Field	Value
dc.title	Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses
dc.contributor.author	Hor, T.S.A.
dc.date.accessioned	2014-10-16T08:42:02Z
dc.date.available	2014-10-16T08:42:02Z
dc.date.issued	1987-01-13
dc.identifier.citation	Hor, T.S.A. (1987-01-13). Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses. Journal of Organometallic Chemistry 319 (2) : 213-217. ScholarBank@NUS Repository.
dc.identifier.issn	0022328X
dc.identifier.uri	http://scholarbank.nus.edu.sg/handle/10635/94948
dc.description.abstract	Trimethylamine N-oxide (TMNO)-initiated decarbonylations of Mo(CO)6 followed by phosphine additions yield the complexes Mo(CO)5(Ph2PCH2PPh2), which consists of a unidentate diphosphine, and the dinuclear phosphine-bridged complexes Mo2(CO)10(μ-Ph2P(CH2)nPPh2) (where n = 2, 3) at ambient temperatures. The IR and NMR (1H and 31P) spectroscopic and structural properties of these complexes are presented and discussed. Some thermal analytical data are summarised. © 1987.
dc.source	Scopus
dc.type	Article
dc.contributor.department	CHEMISTRY
dc.description.sourcetitle	Journal of Organometallic Chemistry
dc.description.volume	319
dc.description.issue	2
dc.description.page	213-217
dc.description.coden	JORCA
dc.identifier.isiut	NOT_IN_WOS
Appears in Collections:	Staff Publications

There are no files associated with this item.

Check