Structural characterisation of the elusive isomer of Os3(CO)10(PPh3)2

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/94901

DC Field	Value
dc.title	Structural characterisation of the elusive isomer of Os3(CO)10(PPh3)2
dc.contributor.author	Leong, W.K.
dc.contributor.author	Liu, Y.
dc.date.accessioned	2014-10-16T08:41:26Z
dc.date.available	2014-10-16T08:41:26Z
dc.date.issued	1999-07-10
dc.identifier.citation	Leong, W.K.,Liu, Y. (1999-07-10). Structural characterisation of the elusive isomer of Os3(CO)10(PPh3)2. Journal of Organometallic Chemistry 584 (1) : 174-178. ScholarBank@NUS Repository.
dc.identifier.issn	0022328X
dc.identifier.uri	http://scholarbank.nus.edu.sg/handle/10635/94901
dc.description.abstract	The X-ray crystal structure of the elusive isomer of Os3(CO)10(PPh3)2 in which the two phosphine ligands are cis and trans with respect to the phosphine-substituted Os-Os edge has been determined; the first direct confirmation for the existence of this isomer in Os3(CO)10(PR3)2 clusters. In contrast to the trans,trans isomer, the cis,trans isomer shows little twisting of the Os(CO)3(PPh3) groupings with respect to the Os(CO)4 unit. © 1999 Elsevier Science S.A. All rights reserved.
dc.source	Scopus
dc.subject	Clusters
dc.subject	Isomers
dc.subject	Osmium
dc.subject	Phosphine
dc.type	Article
dc.contributor.department	CHEMISTRY
dc.description.sourcetitle	Journal of Organometallic Chemistry
dc.description.volume	584
dc.description.issue	1
dc.description.page	174-178
dc.description.coden	JORCA
dc.identifier.isiut	NOT_IN_WOS
Appears in Collections:	Staff Publications

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