Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.jorganchem.2008.09.013
DC Field | Value | |
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dc.title | Spanning [Pt2(μ-S)2(PPh3)4] metalloligands with 1,4-dimercurated durene | |
dc.contributor.author | Cameron, N.E. | |
dc.contributor.author | Linklater, R.A. | |
dc.contributor.author | Henderson, W. | |
dc.contributor.author | Nicholson, B.K. | |
dc.contributor.author | Andy Hor, T.S. | |
dc.date.accessioned | 2014-10-16T08:40:51Z | |
dc.date.available | 2014-10-16T08:40:51Z | |
dc.date.issued | 2008-12-01 | |
dc.identifier.citation | Cameron, N.E., Linklater, R.A., Henderson, W., Nicholson, B.K., Andy Hor, T.S. (2008-12-01). Spanning [Pt2(μ-S)2(PPh3)4] metalloligands with 1,4-dimercurated durene. Journal of Organometallic Chemistry 693 (25) : 3711-3714. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2008.09.013 | |
dc.identifier.issn | 0022328X | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94852 | |
dc.description.abstract | Reaction of the metalloligand [Pt2(μ-S)2(PPh3)4] with 0.5 mol equivalents of durene-1,4-bis(mercuric acetate) [AcOHgC6Me4HgOAc] in methanol gives the polynuclear complex [{Pt2(μ-S)2(PPh3)4}2 (μ-1,4-C6Me4Hg2)]2+ , isolated as its PF6 - and BPh4 - salts. Positive-ion ESI mass spectra indicate that [{Pt2(μ-S)2(PPh3)4}2 (μ-1,4-C6Me4Hg2)]2+ undergoes fragmentation by successive loss of PPh3 ligands, while the ESI mass spectrum of the BPh4 - salt showed additional ions [Pt2(μ-S)2(PPh3)4 (HgC6Me4HgPh)]+ and [Pt2(μ-S)2(PPh3)4HgPh] + as a result of phenyl transfer from BPh4 - to Hg. A single-crystal X-ray structure determination on [{Pt2(μ-S)2(PPh3)4}2 (μ-1,4-C6Me4Hg2)](BPh 4)2 shows that the cation crystallises on a centre of symmetry, with structural features that are comparable to those of the previously characterised complex [Pt2(μ-S)2(PPh3)4HgPh]BPh 4. © 2008 Elsevier B.V. All rights reserved. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2008.09.013 | |
dc.source | Scopus | |
dc.subject | Crystal structure | |
dc.subject | Organomercury complexes | |
dc.subject | Platinum complexes | |
dc.subject | Sulfide complexes | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/j.jorganchem.2008.09.013 | |
dc.description.sourcetitle | Journal of Organometallic Chemistry | |
dc.description.volume | 693 | |
dc.description.issue | 25 | |
dc.description.page | 3711-3714 | |
dc.description.coden | JORCA | |
dc.identifier.isiut | 000260758100005 | |
Appears in Collections: | Staff Publications |
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