Pincer-type di(1,2,4-triazolin-5-ylidene)Pd(ii) complexes and their catalytic activities towards Cu- and amine-free Sonogashira reaction

Abstract

Pd(ii) complexes [PdBr(A-κ3CNC)]Br (1) and [PdBr(B-κ3CNC)]Br (2) with new CNC pincer-type ligands derived from 1,2,4-triazolin-5-ylidenes have been synthesized and characterized by multinuclei NMR spectroscopies, ESI mass spectrometry and X-ray diffraction analysis. The more soluble complex 1 proved to be an efficient pre-catalyst in copper- and amine-free Sonogashira reaction with high turnover numbers. The potential for recycling of the catalyst was also demonstrated. © The Royal Society of Chemistry 2013.