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Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/94467
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dc.titleOxidative addition of substituted arsines and stibines with bis(trifluoromethyl)nitroxyl
dc.contributor.authorAng, H.G.
dc.contributor.authorLien, W.S.
dc.date.accessioned2014-10-16T08:36:22Z
dc.date.available2014-10-16T08:36:22Z
dc.date.issued1980-06
dc.identifier.citationAng, H.G.,Lien, W.S. (1980-06). Oxidative addition of substituted arsines and stibines with bis(trifluoromethyl)nitroxyl. Journal of Fluorine Chemistry 15 (6) : 453-470. ScholarBank@NUS Repository.
dc.identifier.issn00221139
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/94467
dc.description.abstractReactions of bis(trifluoromethyl)nitroxyl with a number of methyl- and trifluoromethyl- substituted arsines and stibines at room temperature lead to the formation of pentavalent arsenic and antimony derivatives, namely (CH3)3-n(CF3)nM[ON(CF3 )2]2 (M = As, n = 0, 1, 2; M = Sb, n = 0, 1). The derivatives yield bis(trifluoromethyl)- hydroxylamine and the corresponding dichlorides on treatment with hydrogen chloride. A free radical mechanism is proposed for the oxidative addition reactions. © 1980.
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleJournal of Fluorine Chemistry
dc.description.volume15
dc.description.issue6
dc.description.page453-470
dc.identifier.isiutNOT_IN_WOS
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