Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.molstruc.2006.03.090
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dc.title | One-dimensional coordination polymers: Cu(II) and Zn(II) complexes of N-(2-pyridylmethyl)-glycine and N-(2-pyridylmethyl)-l-alanine | |
dc.contributor.author | Wang, X. | |
dc.contributor.author | Ranford, J.D. | |
dc.contributor.author | Vittal, J.J. | |
dc.date.accessioned | 2014-10-16T08:35:48Z | |
dc.date.available | 2014-10-16T08:35:48Z | |
dc.date.issued | 2006-08-30 | |
dc.identifier.citation | Wang, X., Ranford, J.D., Vittal, J.J. (2006-08-30). One-dimensional coordination polymers: Cu(II) and Zn(II) complexes of N-(2-pyridylmethyl)-glycine and N-(2-pyridylmethyl)-l-alanine. Journal of Molecular Structure 796 (1-3) : 28-35. ScholarBank@NUS Repository. https://doi.org/10.1016/j.molstruc.2006.03.090 | |
dc.identifier.issn | 00222860 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94419 | |
dc.description.abstract | The crystal structures of three Cu(II) and one Zn(II) complexes of N-(2-pyridylmethyl)-l-glycine (Hpgly) and N-(2-pyridylmethyl)-l-alanine (Hpala) have been described. They are [Cu(pgly)Cl] · H2O (1), [Cu(pala)Cl] · H2O (2), [Cu(pala)(CH3COO)] · 0.75H2O (3), and [Zn(pgly)(NO3)] (4). All these compounds have 1D polymeric structures in the solid state. In 1 and 2, the chloride ions bridge [Cu(pgly)] and [Cu(pala)] fragments, respectively, to generate 1D polymers while the bridging acetate ligands are responsible for the formation of ΛΔΛΔ type spiral polymers in 3. The nitrate ion in 4 is only acting as a terminal ligand while the carboxylate oxygen atom of the pala ligand bridges the Zn(II) centers to form the zigzag coordination polymeric chain. The 1D coordination polymers in 1 and 2 have very similar arrangements although crystallized in different space groups, and host 1D water chains in their crystal lattices. © 2006 Elsevier B.V. All rights reserved. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.molstruc.2006.03.090 | |
dc.source | Scopus | |
dc.subject | Coordination polymer | |
dc.subject | Copper(II) | |
dc.subject | Crystal engineering | |
dc.subject | Reduced Schiff base ligands | |
dc.subject | Water chains | |
dc.subject | Zinc(II) | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/j.molstruc.2006.03.090 | |
dc.description.sourcetitle | Journal of Molecular Structure | |
dc.description.volume | 796 | |
dc.description.issue | 1-3 | |
dc.description.page | 28-35 | |
dc.description.coden | JMOSB | |
dc.identifier.isiut | 000241276300006 | |
Appears in Collections: | Staff Publications |
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