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| Title: | Novel self-assembled decavanadate clusters forming 1D molecular chains and 2D molecular arrays: [HMTA-H⋯H2O][HMTA-CH2OH] [H3V10O28 {Na(H2O)4}]·4H2O and [Na2(H2O)10] [H3V10O28 {Na(H2O)2}]·3H2O | Authors: | Duraisamy, T. Ramanan, A. Vittal, J.J. |
Keywords: | Crystal structure Decavanadates Polyoxovanadates |
Issue Date: | 2000 | Citation: | Duraisamy, T.,Ramanan, A.,Vittal, J.J. (2000). Novel self-assembled decavanadate clusters forming 1D molecular chains and 2D molecular arrays: [HMTA-H⋯H2O][HMTA-CH2OH] [H3V10O28 {Na(H2O)4}]·4H2O and [Na2(H2O)10] [H3V10O28 {Na(H2O)2}]·3H2O. Crystal Engineering 3 (4) : 237-250. ScholarBank@NUS Repository. | Abstract: | Two novel materials, [HMTA-H··H2O] [HMTA-CH2OH] [H3V10O28[Na(H2O) 4)]·4H2O, 1 and [Na2(H2O)10][H3V10O 28[Na(H2O)2)]·3H2O, 2 containing decavanadate clusters interconnected through hydrated sodium cations forming 1D molecular chains and 2D molecular arrays have been self-assembled from acidified, aqueous vanadate solution in the presence of organic bases, hexamethylenetetramine and 1,3,5-triazine respectively. © 2001 Elsevier Science Ltd. All rights reserved. | Source Title: | Crystal Engineering | URI: | http://scholarbank.nus.edu.sg/handle/10635/94396 | ISSN: | 14630184 |
| Appears in Collections: | Staff Publications |
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