1. ScholarBank@NUS
  2. 1. Staff
  3. Staff Publications
Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jssc.2010.07.014
DC FieldValue
dc.titleInvestigations on the solid state interaction between LiAlH4 and NaNH2
dc.contributor.authorChua, Y.S.
dc.contributor.authorWu, G.
dc.contributor.authorXiong, Z.
dc.contributor.authorChen, P.
dc.date.accessioned2014-10-16T08:32:02Z
dc.date.available2014-10-16T08:32:02Z
dc.date.issued2010-09
dc.identifier.citationChua, Y.S., Wu, G., Xiong, Z., Chen, P. (2010-09). Investigations on the solid state interaction between LiAlH4 and NaNH2. Journal of Solid State Chemistry 183 (9) : 2040-2044. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jssc.2010.07.014
dc.identifier.issn00224596
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/94094
dc.description.abstractIn this paper, two LiAlH4NaNH2 samples with LiAlH4 to NaNH2 molar ratio of 1/2 and 2/1 were investigated, respectively. It was observed that both samples evolved 2 equiv H2 in the ball milling process, however, the reaction pathways were different. For the LiAlH4NaNH2 (1/2) sample, Li 3Na(NH2)4 and NaAlH4 were formed through cation exchange between reactants. The NaAlH4 formed further reacts with Li3Na(NH2)4 and NaNH2 to give H2, NaH and LiAlN2H2. For the LiAlH 4NaNH2 (2/1) sample, Li3Na(NH2) 4, LiNH2 and NaAlH4 were formed firstly through the same cation exchange process. The resulting LiNH2 reacts with the remaining LiAlH4 and produces H2 and Li 2AlNH2. © 2010 Elsevier Inc. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jssc.2010.07.014
dc.sourceScopus
dc.subjectCation exchange
dc.subjectHydrogen storage
dc.subjectLiNH2
dc.subjectNaAlH4
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jssc.2010.07.014
dc.description.sourcetitleJournal of Solid State Chemistry
dc.description.volume183
dc.description.issue9
dc.description.page2040-2044
dc.description.codenJSSCB
dc.identifier.isiut000282139600020
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.