Please use this identifier to cite or link to this item: https://doi.org/10.1016/S1387-7003(03)00048-0
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dc.titleHydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3 O19}·4.5H2O
dc.contributor.authorAsnani, M.
dc.contributor.authorRamanan, A.
dc.contributor.authorVittal, J.J.
dc.date.accessioned2014-10-16T08:30:51Z
dc.date.available2014-10-16T08:30:51Z
dc.date.issued2003-05-01
dc.identifier.citationAsnani, M., Ramanan, A., Vittal, J.J. (2003-05-01). Hydrothermal synthesis and structural characterisation of a vanadium (V) borophosphate cluster containing solid: [Co(en)3][enH2]{V3BP3 O19}·4.5H2O. Inorganic Chemistry Communications 6 (5) : 589-592. ScholarBank@NUS Repository. https://doi.org/10.1016/S1387-7003(03)00048-0
dc.identifier.issn13877003
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93994
dc.description.abstractHydrothermal reaction of VOPO4·2H2O and [Co(en)3]Cl3 in sealed borosilicate glass tube yielded a vanadium (V) borophosphate cluster based solid, [Co(en)3][enH2]{V3BP3 O19}·4.5H2O (VBPO). Crystal data: monoclinic space group, P21/c, Z = 4, a = 12.0709(7), b = 14.2261(8) and c = 18.1104(9) Å, β = 95.067(1)0°, V = 3097.8(3) Å3. Single crystal X-ray diffraction studies revealed that discrete [V3BP3O19] clusters are linked to counter cations and water molecules through a complex hydrogen bonding network. © 2003 Elsevier Science B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S1387-7003(03)00048-0
dc.sourceScopus
dc.subjectHydrothermal synthesis
dc.subjectSingle crystal X-ray diffraction
dc.subjectVanadium borophosphate
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/S1387-7003(03)00048-0
dc.description.sourcetitleInorganic Chemistry Communications
dc.description.volume6
dc.description.issue5
dc.description.page589-592
dc.description.codenICCOF
dc.identifier.isiut000181871300040
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