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|Title:||Hydrogen bonding, alkyl chain crystallization and constitutional isomerism in solid-state self-assembly of dodecyloxyisophthalic acid complexes||Authors:||Venkataramanan, B.
|Issue Date:||24-Jan-2005||Citation:||Venkataramanan, B., Ning, Z., Vittal, J.J., Valiyaveettil, S. (2005-01-24). Hydrogen bonding, alkyl chain crystallization and constitutional isomerism in solid-state self-assembly of dodecyloxyisophthalic acid complexes. CrystEngComm 7 : 108-112. ScholarBank@NUS Repository. https://doi.org/10.1039/b417663d||Abstract:||Self-assembly of the molecular complexes of O-alkoxy isophthalic acid (5-C12 and 4-C12) with 4,4′-bipyridine (bipy) in the crystal lattice is described. Complexes 5-C12ISA·bipy and 4-C12ISA·bipy exhibit 3-D supramolecular structures through and interplay of H-bonding, alkyl chain interdigitation, π⋯π and C-H⋯π interactions. The former forms a unique triple helix which further assembles into a 2D network stabilized via π⋯π stacking interactions. The latter forms hydrogen bonded supramolecular sheets. © The Royal Society of Chemistry 2005.||Source Title:||CrystEngComm||URI:||http://scholarbank.nus.edu.sg/handle/10635/93983||ISSN:||14668033||DOI:||10.1039/b417663d|
|Appears in Collections:||Staff Publications|
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