Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2005.10.043
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dc.titleHMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η6-C6Me6, Cp* = η5-C5Me5)
dc.contributor.authorKuan, S.L.
dc.contributor.authorLeong, W.K.
dc.contributor.authorGoh, L.Y.
dc.contributor.authorWebster, R.D.
dc.date.accessioned2014-10-16T08:30:29Z
dc.date.available2014-10-16T08:30:29Z
dc.date.issued2006-02-15
dc.identifier.citationKuan, S.L., Leong, W.K., Goh, L.Y., Webster, R.D. (2006-02-15). HMB and Cp* ruthenium(II) complexes containing bis- and tris-(mercaptomethimazolyl)borate ligands: Synthetic, X-ray structural and electrochemical studies (HMB = η6-C6Me6, Cp* = η5-C5Me5). Journal of Organometallic Chemistry 691 (5) : 907-915. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.10.043
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93962
dc.description.abstractThe reactions of [(HMB)RuCl2]2 with K[HB(mt) 3] and Na[H2B(mt)2] (mt = N-methyl-2- mercaptoimidazol-1-yl) led to the isolation of [(HMB)Ru{HB(mt)3}]Cl (1) (ca. 66% yield) and [(HMB)Ru{H2B(mt)2}]Cl (2) (ca. 70% yield), respectively. The reaction of [Cp*RuOMe]2 with Na[H2B(mt)2] yielded Cp*Ru[H2B(mt) 2] (3) (ca. 85% yield). Single crystal X-ray diffraction analyses were carried out on all three complexes, together with cyclic voltammetric measurements.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2005.10.043
dc.sourceScopus
dc.subject(Mercaptomethimazolyl)borate
dc.subjectCp*/(HMB)ruthenium
dc.subjectElectrochemistry
dc.subjectScorpionate
dc.subjectStructures
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2005.10.043
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume691
dc.description.issue5
dc.description.page907-915
dc.description.codenJORCA
dc.identifier.isiut000235589300011
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