Please use this identifier to cite or link to this item:
https://doi.org/10.1039/C39910000690
DC Field | Value | |
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dc.title | Free radical substitutions of acyloxy groups in carbohydrate α-ketoesters | |
dc.contributor.author | Ferrier, R.J. | |
dc.contributor.author | Lee, C.-K. | |
dc.contributor.author | Wood, T.A. | |
dc.date.accessioned | 2014-10-16T08:29:14Z | |
dc.date.available | 2014-10-16T08:29:14Z | |
dc.date.issued | 1991 | |
dc.identifier.citation | Ferrier, R.J., Lee, C.-K., Wood, T.A. (1991). Free radical substitutions of acyloxy groups in carbohydrate α-ketoesters. Journal of the Chemical Society, Chemical Communications (10) : 690-691. ScholarBank@NUS Repository. https://doi.org/10.1039/C39910000690 | |
dc.identifier.issn | 00224936 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93857 | |
dc.description.abstract | A range of carbohydrate derivatives containing α-ketoester functionality undergo efficient reductive loss of the acyloxy groups when treated with tri-n-butyltin hydride in refluxing benzene and in the presence of azoisobutyronitrile (AIBN) as radical initiator; under similar conditions, but with allyltri-n-butyltin instead of the hydride, efficient α-C-allylation takes place with axial substitution occurring preferentially in compounds with the ketoesters located within conformationally stable pyranoid rings; the methods represent novel ways of deoxygenating carbohydrate derivatives and of introducing branch points. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/C39910000690 | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1039/C39910000690 | |
dc.description.sourcetitle | Journal of the Chemical Society, Chemical Communications | |
dc.description.issue | 10 | |
dc.description.page | 690-691 | |
dc.identifier.isiut | A1991FN78200013 | |
Appears in Collections: | Staff Publications |
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