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Please use this identifier to cite or link to this item: https://doi.org/10.1039/C39900001580
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dc.titleFormation of a novel delocalised diphosphazene upon complexation. The preparation and X-ray structure of Pd2Cl4[(CF 3)2P=N=PPh3]2
dc.contributor.authorAng, H.G.
dc.contributor.authorCai, Y.M.
dc.contributor.authorKwik, W.L.
dc.contributor.authorRheingold, A.L.
dc.date.accessioned2014-10-16T08:29:00Z
dc.date.available2014-10-16T08:29:00Z
dc.date.issued1990
dc.identifier.citationAng, H.G., Cai, Y.M., Kwik, W.L., Rheingold, A.L. (1990). Formation of a novel delocalised diphosphazene upon complexation. The preparation and X-ray structure of Pd2Cl4[(CF 3)2P=N=PPh3]2. Journal of the Chemical Society, Chemical Communications (22) : 1580-1581. ScholarBank@NUS Repository. https://doi.org/10.1039/C39900001580
dc.identifier.issn00224936
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93836
dc.description.abstractReaction of (CF3)2P-N=PPh3(L) with PdCl2 in dichloromethane gives Pd2Cl4[(CF 3)2P=N=PPh3]2, 1 in which L has been shown from spectroscopic and X-ray crystallographic analyses to assume an uncharged non-linear electronic structure [Ph3P=N=P(CF 3)2], where the P-N and N-P bonds are equidistant and the PNP segment is highly delocalised.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/C39900001580
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1039/C39900001580
dc.description.sourcetitleJournal of the Chemical Society, Chemical Communications
dc.description.issue22
dc.description.page1580-1581
dc.identifier.isiutA1990EL42500017
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