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https://doi.org/10.1039/b811493e
DC Field | Value | |
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dc.title | Formation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond | |
dc.contributor.author | Li, J. | |
dc.contributor.author | Hor, T.S.A. | |
dc.date.accessioned | 2014-10-16T08:28:59Z | |
dc.date.available | 2014-10-16T08:28:59Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Li, J., Hor, T.S.A. (2008). Formation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond. Dalton Transactions (42) : 5708-5711. ScholarBank@NUS Repository. https://doi.org/10.1039/b811493e | |
dc.identifier.issn | 14779226 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93834 | |
dc.description.abstract | Redox addition of the Pd-Pd bond in [Pd2Cl2(dppm) 2] across S-S or Se-Se bond in [Pt(X4- κ2X1,X4)(P-P)] (X = S, Se; P-P = dppe or 2 × PPh3; dppm = bis(diphenylphosphino)methane, dppe = bis(diphenylphosphino)ethane) leads to the isolation of [PtPd 2(μ3-X)2(P-P)(dppmX-κ2X, P4)2]2+ and represents an atom-economy process that converts chalcogen-rich complexes to heterometallic chalcogenide aggregates. Activation of the [PtX4] ring is achieved by tetrachalcogenide reduction and dual oxidation of palladium and phosphine. © 2008 The Royal Society of Chemistry. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/b811493e | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1039/b811493e | |
dc.description.sourcetitle | Dalton Transactions | |
dc.description.issue | 42 | |
dc.description.page | 5708-5711 | |
dc.identifier.isiut | 000260227000006 | |
Appears in Collections: | Staff Publications |
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