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Title: First examples of AuI-X-AgI halonium cations (X = Cl and Br)
Authors: Zhang, K.
Prabhavathy, J. 
Yip, J.H.K. 
Koh, L.L. 
Tan, G.K.
Vittal, J.J. 
Issue Date: 16-Jul-2003
Citation: Zhang, K., Prabhavathy, J., Yip, J.H.K., Koh, L.L., Tan, G.K., Vittal, J.J. (2003-07-16). First examples of AuI-X-AgI halonium cations (X = Cl and Br). Journal of the American Chemical Society 125 (28) : 8452-8453. ScholarBank@NUS Repository.
Abstract: Novel {[(μ-PAnP)(AuX)2]2Ag}+SbF6 - halonium ions (X = Cl, Br; PAnP = 9,10-bis(diphenylphosphino)anthracene) were synthesized from the reactions between (μ-PAnP)(AuX)2 and 1/2 mol equiv of AgSbF6. The compounds feature an unprecedented distorted Au4X4 dodecahedron which encapsulates a silver(I) ion at its center. The halonium ions are stabilized by collective actions of metallophilic Au-Ag, aromatic π-π, and Ag-X interactions. Copyright © 2003 American Chemical Society.
Source Title: Journal of the American Chemical Society
ISSN: 00027863
DOI: 10.1021/ja035064z
Appears in Collections:Staff Publications

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