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|Title:||Ethenethiol and 1-propene-1-thiol: a photoelectron spectroscopic study||Authors:||Chin, W.S.
|Issue Date:||18-Mar-1994||Citation:||Chin, W.S.,Mok, C.Y.,Huang, H.H. (1994-03-18). Ethenethiol and 1-propene-1-thiol: a photoelectron spectroscopic study. Journal of Electron Spectroscopy and Related Phenomena 67 (1) : 173-179. ScholarBank@NUS Repository.||Abstract:||Ethenethiol and 1-propene-1-thiol were produced through the thermolysis of thiirane and 2-methylthiirane, respectively, under reduced pressure in a flow system. The photoelectron spectra of the olefin thiols are characterised by the presence of a sharp first band which is well separated from the other bands by more than 2 eV. The spectra are discussed with the aid of AM1 and ab initio SCF MO calculations, and a diagram which correlates the binding energies of the first three orbitals, viz. πCCS *, πCCS and σCS, with those of the corresponding orbitals of related molecules. © 1994.||Source Title:||Journal of Electron Spectroscopy and Related Phenomena||URI:||http://scholarbank.nus.edu.sg/handle/10635/93770||ISSN:||03682048|
|Appears in Collections:||Staff Publications|
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