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https://scholarbank.nus.edu.sg/handle/10635/93748
DC Field | Value | |
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dc.title | Encounter of an inferior intramolecular cyclization in an approach toward the synthesis of 10-oxo-2-thia[3.2]metacyclophane: Preparation of two isomeric dioxo-2,19-dithia[3.2.3.2]metacyclophanes | |
dc.contributor.author | Lai, Y.-H. | |
dc.contributor.author | Yeo, L.-H. | |
dc.date.accessioned | 2014-10-16T08:27:55Z | |
dc.date.available | 2014-10-16T08:27:55Z | |
dc.date.issued | 1988-07 | |
dc.identifier.citation | Lai, Y.-H.,Yeo, L.-H. (1988-07). Encounter of an inferior intramolecular cyclization in an approach toward the synthesis of 10-oxo-2-thia[3.2]metacyclophane: Preparation of two isomeric dioxo-2,19-dithia[3.2.3.2]metacyclophanes. Heterocycles 27 (7) : 1629-1636. ScholarBank@NUS Repository. | |
dc.identifier.issn | 03855414 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93748 | |
dc.description.abstract | The sodium sulfide coupling of 1,2-bis(3-bromomethyl)phenytethanone, Prepared in seven steps from m,α-dichlorotoluene, was attempted but failed to yield the. desired 10-oxo-2-thia[3,2]metacyclophane. This is, attributed to unfavoralle. geometry in the thiacyclophane, due to introduction of the sp2 carbonyl carbon. Two isomeric dioxo-dithia[3,2.3,2]metacyclophanes were however isolated from the coupling reaction. Both these cyclophanes were found to be conformationally highly mobile by variable-temperature NMR studies. © 1988. | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Heterocycles | |
dc.description.volume | 27 | |
dc.description.issue | 7 | |
dc.description.page | 1629-1636 | |
dc.description.coden | HTCYA | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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