Crystallographic realization of the mathematically predicted densest all-pentagon packing lattice by C5-symmetric "sticky" fluoropentamers

Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201101553

Title:	Crystallographic realization of the mathematically predicted densest all-pentagon packing lattice by C5-symmetric "sticky" fluoropentamers
Authors:	Ren, C. Zhou, F. Qin, B. Ye, R. Shen, S. Su, H. Zeng, H.
Keywords:	fivefold symmetry hydrogen bonds macrocycles pentagonal molecules supramolecular chemistry
Issue Date:	4-Nov-2011
Citation:	Ren, C., Zhou, F., Qin, B., Ye, R., Shen, S., Su, H., Zeng, H. (2011-11-04). Crystallographic realization of the mathematically predicted densest all-pentagon packing lattice by C5-symmetric "sticky" fluoropentamers. Angewandte Chemie - International Edition 50 (45) : 10612-10615. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201101553
Abstract:	Regular pentagonal adhesive tiles were obtained by designing a cyclic fluoropentamer with an internal CF⋯HN H-bonded network and "sticky" edges that can glue the molecules together through intermolecular CArH⋯O=C H bonds. In the crystal they form the mathematically predicted densest all-pentagon 2D lattice with a packing density of 0.921 (see picture). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title:	Angewandte Chemie - International Edition
URI:	http://scholarbank.nus.edu.sg/handle/10635/93507
ISSN:	14337851
DOI:	10.1002/anie.201101553
Appears in Collections:	Staff Publications

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