Please use this identifier to cite or link to this item:
Title: Clusters in bis-tridentate tethered domains of an iron chelating drug
Authors: Henderson, W.
Koh, L.L. 
Ranford, J.D. 
Robinson, W.T.
Svensson, J.O.
Vittal, J.J. 
Wang, Y.M.
Xu, Y.
Issue Date: 7-Oct-1999
Citation: Henderson, W.,Koh, L.L.,Ranford, J.D.,Robinson, W.T.,Svensson, J.O.,Vittal, J.J.,Wang, Y.M.,Xu, Y. (1999-10-07). Clusters in bis-tridentate tethered domains of an iron chelating drug. Journal of the Chemical Society - Dalton Transactions (19) : 3341-3344. ScholarBank@NUS Repository.
Abstract: The tridentate metal binding domains of iron chelating agents have been tethered via a variable length methylene (CH2)n linker (n = 1, 2, 4, 6, 8, 10, 14). The single-crystal X-ray structures of monomeric ([Fe(HL8)]·2.5H2O n = 8; H4L8 is 1,10-decanedioyl di(salicylaldehyde hydrazone)) and dimeric ([{Fe(H2PL4)}2]Cl2·2H 2O n = 4; H4PL4 is 1,6-hexanedioyl di(pyridoxal hydrazone)) iron(III) complexes have been determined. The complexes exhibit oligomerism: with chain lengths of n≥6 monomers are prevalent whereas for shorter chains this is not possible and a series of clusters exist as shown by ESMS and molecular modelling. © The Royal Society of Chemistry 1999.
Source Title: Journal of the Chemical Society - Dalton Transactions
ISSN: 03009246
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

checked on Jan 26, 2020

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.