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https://doi.org/10.3390/molecules18044282
DC Field | Value | |
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dc.title | Antioxidant activity and proanthocyanidin profile of selliguea feei rhizomes | |
dc.contributor.author | Fu, C. | |
dc.contributor.author | Wang, H. | |
dc.contributor.author | Ng, W.L. | |
dc.contributor.author | Song, L. | |
dc.contributor.author | Huang, D. | |
dc.date.accessioned | 2014-10-16T08:20:36Z | |
dc.date.available | 2014-10-16T08:20:36Z | |
dc.date.issued | 2013-04 | |
dc.identifier.citation | Fu, C., Wang, H., Ng, W.L., Song, L., Huang, D. (2013-04). Antioxidant activity and proanthocyanidin profile of selliguea feei rhizomes. Molecules 18 (4) : 4282-4292. ScholarBank@NUS Repository. https://doi.org/10.3390/molecules18044282 | |
dc.identifier.issn | 14203049 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93118 | |
dc.description.abstract | Proanthocyanidins from the rhizomes of Selliguea feei (PSFs) were solvent-extracted and fractionated by Sephadex LH-20 column chromatography to give a 2.42% isolated yield (dry matter basis). 1H-NMR spectroscopy revealed the mean degree of polymerization (mDP) to be 2.6. 13C-NMR analysis showed typical signals for afzelechin/epiafzelechin units. Clear peaks at 76 ppm and 84 ppm indicated that both stereoisomers (afzelechin/ epiafzelechin) are present. In agreement with the NMR spectra, the ESI-MS spectrum indicated that PSFs are mainly monomers to trimers consisting of afzelechin/epiafzelechin units with A-type and B-type interflavanyl linkages. A trimer was purified and identified as demethylated selligueain B. Thiolysis confirmed the structure and the thiolytic products, methyl 2-[(2R, 3R, 4S)-3,5,7-trihydroxy-2-(4-hydroxyphenyl)chroman-4-yl]acetate (1) and 4β-(carboxymethyl)sulphanylepiafzelechin-(2β→O→7, 4β→8)-epiafzelechin methyl ester (2), were purified and characterized. Selligueain A, demethylated selligueain B, compounds 1 and 2 possess high antioxidant capacity at 1.18 × 104, 1.16 × 10 4, 0.95 × 104 and 1.29 × 104 μmol TE/g, respectively. © 2013 by the authors. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.3390/molecules18044282 | |
dc.source | Scopus | |
dc.subject | Antioxidant activity | |
dc.subject | Proanthocyanidins | |
dc.subject | Selliguea feei | |
dc.subject | Thiolysis | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.3390/molecules18044282 | |
dc.description.sourcetitle | Molecules | |
dc.description.volume | 18 | |
dc.description.issue | 4 | |
dc.description.page | 4282-4292 | |
dc.description.coden | MOLEF | |
dc.identifier.isiut | 000318020100043 | |
Appears in Collections: | Staff Publications |
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