Please use this identifier to cite or link to this item: https://doi.org/10.1016/S1472-7862(03)00079-0
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dc.titleA urea-incorporated receptor for aromatic carboxylate anion recognition
dc.contributor.authorFan, A.
dc.contributor.authorHong, H.K.
dc.contributor.authorValiyaveettil, S.
dc.contributor.authorVittal, J.J.
dc.date.accessioned2014-10-16T08:19:36Z
dc.date.available2014-10-16T08:19:36Z
dc.date.issued2002-01
dc.identifier.citationFan, A.,Hong, H.K.,Valiyaveettil, S.,Vittal, J.J. (2002-01). A urea-incorporated receptor for aromatic carboxylate anion recognition. Journal of Supramolecular Chemistry 2 (1-3) : 247-254. ScholarBank@NUS Repository. <a href="https://doi.org/10.1016/S1472-7862(03)00079-0" target="_blank">https://doi.org/10.1016/S1472-7862(03)00079-0</a>
dc.identifier.issn14727862
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93031
dc.description.abstractA neutral urea incorporated anion receptor 1 with a tripodal pseudocavity was synthesized in good yield. The influence of preorganization and rigidity of the receptors towards anion recognition was evaluated using rigid (1) and flexible (2) receptors. Binding affinities were investigated using 1H NMR and luminescence titration methods. Receptor 1 showed high binding affinities with 1:1 stoichiometry for carboxylate anions in polar solvents. No binding was observed with small anions, presumably due to the large cavity and the rigidity of the receptor. © 2003 Elsevier Ltd. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S1472-7862(03)00079-0
dc.sourceScopus
dc.subjectAnion receptor
dc.subjectCarboxylate anion
dc.subjectHost-guest chemistry
dc.subjectHydrogen bonds
dc.subjectPreorganization
dc.subjectUrea
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/S1472-7862(03)00079-0
dc.description.sourcetitleJournal of Supramolecular Chemistry
dc.description.volume2
dc.description.issue1-3
dc.description.page247-254
dc.identifier.isiutNOT_IN_WOS
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