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|Title:||A thermometric enthalpy titration study of the cadmium/ferricyanide system||Authors:||Hill, J.O.
|Issue Date:||8-Oct-1991||Citation:||Hill, J.O.,Lim, S. (1991-10-08). A thermometric enthalpy titration study of the cadmium/ferricyanide system. Thermochimica Acta 188 (2) : 249-254. ScholarBank@NUS Repository.||Abstract:||A thermometric enthalpy titration study of the cadmium/ferricyanide system in aqueous solution has revealed that in the presence of excess cadmium ion, a single cadmium/ferricyanide complex species predominates in solution with a stoichiometry of [Cd10(Fe(CN)6)7]-. In the presence of excess ferricyanide, a single cadmium/ferricyanide complex species again predominates but with a stoichiometry of [Cd(Fe(CN)6)2]4-. It is apparent that the relative concentrations of Cd2+ and [Fe(CN)6]3- control the number and stoichiometry of cadmium/ferricyanide species formed in aqueous solution. © 1991.||Source Title:||Thermochimica Acta||URI:||http://scholarbank.nus.edu.sg/handle/10635/93024||ISSN:||00406031|
|Appears in Collections:||Staff Publications|
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