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|Title:||A novel method for the synthesis of perovskite-type mixed metal oxides by the inverse microemulsion technique||Authors:||Gan, L.M.
|Issue Date:||1996||Citation:||Gan, L.M.,Zhang, L.H.,Chan, H.S.O.,Chew, C.H.,Loo, B.H. (1996). A novel method for the synthesis of perovskite-type mixed metal oxides by the inverse microemulsion technique. Journal of Materials Science 31 (4) : 1071-1079. ScholarBank@NUS Repository.||Abstract:||Nanoparticles of lanthanum-nickel, lanthanum-copper and barium-lead oxalates with the metal molar ratios of 1:1, 2:1 and 1:1, respectively, have been successfully synthesized in inverse microemulsions. These metal oxalate particles of about 20 nm diameter were readily calcined into single-phase perovskite-type LaNiO3, La2CuO4 and BaPbO3. The calcination temperatures for these metal oxalates were generally 100-250°C lower than those for the metal oxalates prepared by the conventional aqueous solution precipitation method. The substantial reduction in the calcination temperatures is attributed to the formation of uniform, near-spherical nanoparticles of the metal oxalate precursors obtained by the unique inverse microemulsion technique. © 1996 Chapman & Hall.||Source Title:||Journal of Materials Science||URI:||http://scholarbank.nus.edu.sg/handle/10635/92979||ISSN:||00222461|
|Appears in Collections:||Staff Publications|
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