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Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/92967
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dc.titleA new route to metal-halogen bond formation in metal carbonyl clusters: Crystal structure of the fluorinated cluster (μ-H)Os3(CO) 10( AsPh3)F
dc.contributor.authorAng, H.G.
dc.contributor.authorAng, S.G.
dc.contributor.authorLeong, W.Y.
dc.contributor.authorWinfield, J.
dc.date.accessioned2014-10-16T08:18:49Z
dc.date.available2014-10-16T08:18:49Z
dc.date.issued1998-02-27
dc.identifier.citationAng, H.G.,Ang, S.G.,Leong, W.Y.,Winfield, J. (1998-02-27). A new route to metal-halogen bond formation in metal carbonyl clusters: Crystal structure of the fluorinated cluster (μ-H)Os3(CO) 10( AsPh3)F. Journal of Fluorine Chemistry 88 (1) : 5-8. ScholarBank@NUS Repository.
dc.identifier.issn00221139
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/92967
dc.description.abstract(μ-H)Os3(CO) 10(EPh3) [ON(CF3)2] (E = P, As, Sb) and (μ-H) Os3 (CO) 11[ON(CF3)2] react with HX (X = F, Cl, Br, I) to afford (CF3)2NOH and (μ-H)Os3(CO) 10(EPh3) (X) or (μ-H)Os3(CO) 11(X). The reaction of (μ-H)Os3(CO) 10( AsPh3) [ON(CF3)2] with HF gives two isomers, one of which was established from X-ray crystallography to be (μ-H)Os3(CO) 10( AsPh3) (F) with AsPh3 and F bonded to the same Os centre. The Os-F bond and the Os-CO bond trans to it are relatively short. © 1998 Elsevier Science S.A. All rights reserved.
dc.sourceScopus
dc.subjectFluorosubstituted triosmium clusters
dc.subjectOsmium-halogen bond
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleJournal of Fluorine Chemistry
dc.description.volume88
dc.description.issue1
dc.description.page5-8
dc.identifier.isiutNOT_IN_WOS
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