(4,4′-bipyridine)bis[bis(N,N-diethyldithiocarbamato) zinc(II)]

Please use this identifier to cite or link to this item: https://doi.org/10.1002/aoc.421

Title:	(4,4′-bipyridine)bis[bis(N,N-diethyldithiocarbamato) zinc(II)]
Authors:	Lai, C.S. Tiekink, E.R.T.
Keywords:	Crystal structure Diimine adduct Dithiocarbamate Zinc
Issue Date:	1-Apr-2003
Citation:	Lai, C.S., Tiekink, E.R.T. (2003-04-01). (4,4′-bipyridine)bis[bis(N,N-diethyldithiocarbamato) zinc(II)]. Applied Organometallic Chemistry 17 (4) : 253-254. ScholarBank@NUS Repository. https://doi.org/10.1002/aoc.421
Abstract:	The structure of [Zn(S2CNEt2)2]2(4,4′-bipy) shows two independent dimeric molecules, one located about a centre of inversion, the other lying on a two fold axis containing the zinc atoms. Bidentate coordination by the dithiocarbamate ligands and a distorted square pyramidal geometry are found for two of zinc atoms whereas for the third zinc atom, the geometry is intermediate between square pyramidal and trigonal bipyramidal, a result that underscores the flexibility of coordination in these systems. Copyright © 2003 John Wiley & Sons, Ltd.
Source Title:	Applied Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/92872
ISSN:	02682605
DOI:	10.1002/aoc.421
Appears in Collections:	Staff Publications

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