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Please use this identifier to cite or link to this item: https://doi.org/10.1002/smll.201203112
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dc.titleTwo-phase synthesis of small thiolate-protected Au15 and Au 18 nanoclusters
dc.contributor.authorYao, Q.
dc.contributor.authorYu, Y.
dc.contributor.authorYuan, X.
dc.contributor.authorYu, Y.
dc.contributor.authorXie, J.
dc.contributor.authorLee, J.Y.
dc.date.accessioned2014-10-09T07:05:18Z
dc.date.available2014-10-09T07:05:18Z
dc.date.issued2013-08-26
dc.identifier.citationYao, Q., Yu, Y., Yuan, X., Yu, Y., Xie, J., Lee, J.Y. (2013-08-26). Two-phase synthesis of small thiolate-protected Au15 and Au 18 nanoclusters. Small 9 (16) : 2696-2701. ScholarBank@NUS Repository. https://doi.org/10.1002/smll.201203112
dc.identifier.issn16136810
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/90441
dc.description.abstractA one-pot two-phase method for the direct synthesis of small Au (Au 15 and Au18) nanoclusters (NCs) of high purity is developed. A mild reductant is combined with two equilibria (i.e., equilibrium partition and aggregation-dissociation equilibrium) to provide a constant reaction environment for the formation of monodisperse small Au NCs. The pH sensitivity of the aggregation-dissociation equilibrium is used to tailor the cluster size. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/smll.201203112
dc.sourceScopus
dc.subjectaggregation-dissociation equilibria
dc.subjectgold
dc.subjectmonodisperse
dc.subjectnanoclusters
dc.subjectsynthesis
dc.typeArticle
dc.contributor.departmentCHEMICAL & BIOMOLECULAR ENGINEERING
dc.description.doi10.1002/smll.201203112
dc.description.sourcetitleSmall
dc.description.volume9
dc.description.issue16
dc.description.page2696-2701
dc.description.codenSMALB
dc.identifier.isiut000327738600007
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