Please use this identifier to cite or link to this item: https://doi.org/10.1021/ma0607362
DC FieldValue
dc.titlePreparation of polymer-silicon(100) hybrids via interface-initiated reversible addition-fragmentation chain-transfer (RAFT) polymerization
dc.contributor.authorPeng, Q.
dc.contributor.authorLai, D.M.Y.
dc.contributor.authorKang, E.T.
dc.contributor.authorNeoh, K.G.
dc.date.accessioned2014-10-09T06:59:13Z
dc.date.available2014-10-09T06:59:13Z
dc.date.issued2006-08-08
dc.identifier.citationPeng, Q., Lai, D.M.Y., Kang, E.T., Neoh, K.G. (2006-08-08). Preparation of polymer-silicon(100) hybrids via interface-initiated reversible addition-fragmentation chain-transfer (RAFT) polymerization. Macromolecules 39 (16) : 5577-5582. ScholarBank@NUS Repository. https://doi.org/10.1021/ma0607362
dc.identifier.issn00249297
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/89916
dc.description.abstractThe surface modification of (100)-oriented single crystal silicon with covalently bonded (Si-C bonded) polymer brushes by interface-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was demonstrated. The simple approach of immobilizing the thiocarbonyl-thioether compound on a hydrogen-terminated Si (100) surface via the radical stabilizing group provided stable Si-C bonded chain transfer agent (CTA). The orthogonal surface chemistry or spatial ordering of the block sequence in grafted diblock copolymers, produced by the interface-initiated RAFT polymerization, was revealed by X-ray photoelectron spectroscopy (XPS) and by Ar+ beam etching and time-of-flight secondary ion mass spectroscopy (ToF-SIMS). 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) were selected as the model monomers for the preparation of polymer-Si hybrids via interface-initiated (RAFT) graft polymerization.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/ma0607362
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMICAL & BIOMOLECULAR ENGINEERING
dc.description.doi10.1021/ma0607362
dc.description.sourcetitleMacromolecules
dc.description.volume39
dc.description.issue16
dc.description.page5577-5582
dc.description.codenMAMOB
dc.identifier.isiut000239400800058
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