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https://doi.org/10.1021/ma0607362
DC Field | Value | |
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dc.title | Preparation of polymer-silicon(100) hybrids via interface-initiated reversible addition-fragmentation chain-transfer (RAFT) polymerization | |
dc.contributor.author | Peng, Q. | |
dc.contributor.author | Lai, D.M.Y. | |
dc.contributor.author | Kang, E.T. | |
dc.contributor.author | Neoh, K.G. | |
dc.date.accessioned | 2014-10-09T06:59:13Z | |
dc.date.available | 2014-10-09T06:59:13Z | |
dc.date.issued | 2006-08-08 | |
dc.identifier.citation | Peng, Q., Lai, D.M.Y., Kang, E.T., Neoh, K.G. (2006-08-08). Preparation of polymer-silicon(100) hybrids via interface-initiated reversible addition-fragmentation chain-transfer (RAFT) polymerization. Macromolecules 39 (16) : 5577-5582. ScholarBank@NUS Repository. https://doi.org/10.1021/ma0607362 | |
dc.identifier.issn | 00249297 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/89916 | |
dc.description.abstract | The surface modification of (100)-oriented single crystal silicon with covalently bonded (Si-C bonded) polymer brushes by interface-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was demonstrated. The simple approach of immobilizing the thiocarbonyl-thioether compound on a hydrogen-terminated Si (100) surface via the radical stabilizing group provided stable Si-C bonded chain transfer agent (CTA). The orthogonal surface chemistry or spatial ordering of the block sequence in grafted diblock copolymers, produced by the interface-initiated RAFT polymerization, was revealed by X-ray photoelectron spectroscopy (XPS) and by Ar+ beam etching and time-of-flight secondary ion mass spectroscopy (ToF-SIMS). 2-hydroxyethyl methacrylate (HEMA) and methyl methacrylate (MMA) were selected as the model monomers for the preparation of polymer-Si hybrids via interface-initiated (RAFT) graft polymerization. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/ma0607362 | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMICAL & BIOMOLECULAR ENGINEERING | |
dc.description.doi | 10.1021/ma0607362 | |
dc.description.sourcetitle | Macromolecules | |
dc.description.volume | 39 | |
dc.description.issue | 16 | |
dc.description.page | 5577-5582 | |
dc.description.coden | MAMOB | |
dc.identifier.isiut | 000239400800058 | |
Appears in Collections: | Staff Publications |
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