Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/89911
DC Field | Value | |
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dc.title | Preparation of jellyfish-shaped amphiphilic block-graft copolymers consisting of a poly(ε-caprolactone)-block-poly(pentafluorostyrene) ring and poly(ethylene glycol) lateral brushes | |
dc.contributor.author | Cai, T. | |
dc.contributor.author | Yang, W.J. | |
dc.contributor.author | Neoh, K.-G. | |
dc.contributor.author | Kang, E.-T. | |
dc.date.accessioned | 2014-10-09T06:59:09Z | |
dc.date.available | 2014-10-09T06:59:09Z | |
dc.date.issued | 2012-04 | |
dc.identifier.citation | Cai, T., Yang, W.J., Neoh, K.-G., Kang, E.-T. (2012-04). Preparation of jellyfish-shaped amphiphilic block-graft copolymers consisting of a poly(ε-caprolactone)-block-poly(pentafluorostyrene) ring and poly(ethylene glycol) lateral brushes. Polymer Chemistry 3 (4) : 1061-1068. ScholarBank@NUS Repository. | |
dc.identifier.issn | 17599954 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/89911 | |
dc.description.abstract | A versatile synthetic route to jellyfish-shaped amphiphilic block-graft copolymers with a hydrophobic ring of controllable dimensions, consisting of tailored length and number of poly(ε-caprolactone) (PCL) and poly(pentafluorostyrene) (PFS) blocks, and hydrophilic poly(ethylene glycol) (PEG) brushes, has been developed via the combination of ring-opening polymerization (ROP), atom transfer radical polymerization (ATRP), alkyne-azide click reaction and thiol-para-fluorine click reaction. The chemical structures and compositions of all the polymers were characterized by nuclear magnetic resonance (NMR) spectroscopy, gel permeation chromatography (GPC), thermogravimetric analyses (TGA), and X-ray photoelectron spectroscopy (XPS). The morphology of micelles from self-assembly of the cyclic-[PCL-b-P(FS-g-PEG)] copolymer in an aqueous medium was investigated by field emission scanning electron microscopy (FESEM). © 2012 The Royal Society of Chemistry. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/c2py00609j | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMICAL & BIOMOLECULAR ENGINEERING | |
dc.description.sourcetitle | Polymer Chemistry | |
dc.description.volume | 3 | |
dc.description.issue | 4 | |
dc.description.page | 1061-1068 | |
dc.identifier.isiut | 000301199600031 | |
Appears in Collections: | Staff Publications |
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