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Title: Benzothiazolin-2-ylidene and azole mixed-ligand complexes of palladium
Authors: Yen, S.K. 
Koh, L.L. 
Huynh, H.V. 
Hor, T.S.A. 
Keywords: Carbene ligands
N, S ligands
Nitrogen heterocycles
Issue Date: Oct-2009
Citation: Yen, S.K., Koh, L.L., Huynh, H.V., Hor, T.S.A. (2009-10). Benzothiazolin-2-ylidene and azole mixed-ligand complexes of palladium. European Journal of Inorganic Chemistry (28) : 4288-4297. ScholarBank@NUS Repository.
Abstract: A series of mixed-ligand, mononuclear complexes trans[PdX 2(NSHC)(azole)] [NSHC = N,S-heterocyclic carbene; azole = imidazole, l-(2,4,6-trimethylphenyl)-1H-imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X-ray single-crystal diffrac-tion. These complexes catalyse the sp2-sp3 cross-coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers, © Wiley-VCH Verlag GmbH & Co. KGaA.
Source Title: European Journal of Inorganic Chemistry
ISSN: 14341948
DOI: 10.1002/ejic.200900447
Appears in Collections:Staff Publications

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