Please use this identifier to cite or link to this item:
https://doi.org/10.1021/la0361159
DC Field | Value | |
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dc.title | Acetate stabilization of metal nanoparticles and its role in the preparation of metal nanoparticles in ethylene glycol | |
dc.contributor.author | Yang, J. | |
dc.contributor.author | Deivaraj, T.C. | |
dc.contributor.author | Too, H.-P. | |
dc.contributor.author | Lee, J.Y. | |
dc.date.accessioned | 2014-10-09T06:42:58Z | |
dc.date.available | 2014-10-09T06:42:58Z | |
dc.date.issued | 2004-05-11 | |
dc.identifier.citation | Yang, J., Deivaraj, T.C., Too, H.-P., Lee, J.Y. (2004-05-11). Acetate stabilization of metal nanoparticles and its role in the preparation of metal nanoparticles in ethylene glycol. Langmuir 20 (10) : 4241-4245. ScholarBank@NUS Repository. https://doi.org/10.1021/la0361159 | |
dc.identifier.issn | 07437463 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/88495 | |
dc.description.abstract | Acetate-stabilized ruthenium nanoparticles were prepared by the NaBH 4 reduction of the metal precursor salt at room temperature, Nanoparticles with a mean diameter of 2.20 nm and a standard deviation of 1.03 nm could be obtained under experimental conditions. The Ru nanoparticles so obtained could be easily extracted to a toluene solution of alkylamine, giving rise to alkylamine-stabilized Ru nanoparticles with a mean diameter of 2.96 nm and a standard deviation of 0.92 nm, The new found role of acetate stabilization was used to formulate a mechanism for the formation of metal (Pt, Ru) nanoparticles in ethylene glycol. In this mechanism metal nanoparticles are stabilized in ethylene glycol by adsorbed acetate ions, which are produced as a product of the OH - catalyzed reaction between the metal precursor salt and ethylene glycol. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/la0361159 | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMICAL & BIOMOLECULAR ENGINEERING | |
dc.contributor.department | SINGAPORE-MIT ALLIANCE | |
dc.description.doi | 10.1021/la0361159 | |
dc.description.sourcetitle | Langmuir | |
dc.description.volume | 20 | |
dc.description.issue | 10 | |
dc.description.page | 4241-4245 | |
dc.description.coden | LANGD | |
dc.identifier.isiut | 000221319400062 | |
Appears in Collections: | Staff Publications |
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