Please use this identifier to cite or link to this item:
Title: Crystal structure of a superionic conductor, Li7P3S11
Authors: Yamane, H.
Shibata, M.
Shimane, Y.
Junke, T.
Seino, Y.
Adams, S. 
Minami, K.
Hayashi, A.
Tatsumisago, M.
Keywords: Crystal structure
Glass ceramics
Lithium ion conductor
Lithium phosphorous sulfide
Issue Date: Jun-2007
Citation: Yamane, H., Shibata, M., Shimane, Y., Junke, T., Seino, Y., Adams, S., Minami, K., Hayashi, A., Tatsumisago, M. (2007-06). Crystal structure of a superionic conductor, Li7P3S11. Solid State Ionics 178 (15-18) : 1163-1167. ScholarBank@NUS Repository.
Abstract: A synchrotron X-ray powder diffraction pattern was measured for a lithium superionic conductor, Li7P3S11, which has a high conductivity of 3.2 × 10- 3 S cm- 1 at room temperature and a low activation energy of 12 kJ mol- 1 [Mizuno et al., Solid State Ionics, vol. 177 (2006) 2721]. The crystal structure was solved by a direct space global optimization technique and refined by the Rietveld method. The compound crystallizes in a triclinic cell, space group P-1, a = 12.5009(3) Å, b = 6.03160(17) Å, c = 12.5303(3) Å, α = 102.845(3)°,  β = 113.2024(18)°, γ = 74.467(3)°. PS4 tetrahedra and P2S7 ditetrahedra are contained in the structure and Li ions are situated between them. © 2007 Elsevier B.V. All rights reserved.
Source Title: Solid State Ionics
ISSN: 01672738
DOI: 10.1016/j.ssi.2007.05.020
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.


checked on Oct 14, 2021


checked on Oct 14, 2021

Page view(s)

checked on Oct 14, 2021

Google ScholarTM



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.