Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.ssi.2007.05.020
| Title: | Crystal structure of a superionic conductor, Li7P3S11 | Authors: | Yamane, H. Shibata, M. Shimane, Y. Junke, T. Seino, Y. Adams, S. Minami, K. Hayashi, A. Tatsumisago, M. |
Keywords: | Crystal structure Glass ceramics Lithium ion conductor Lithium phosphorous sulfide |
Issue Date: | Jun-2007 | Citation: | Yamane, H., Shibata, M., Shimane, Y., Junke, T., Seino, Y., Adams, S., Minami, K., Hayashi, A., Tatsumisago, M. (2007-06). Crystal structure of a superionic conductor, Li7P3S11. Solid State Ionics 178 (15-18) : 1163-1167. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ssi.2007.05.020 | Abstract: | A synchrotron X-ray powder diffraction pattern was measured for a lithium superionic conductor, Li7P3S11, which has a high conductivity of 3.2 × 10- 3 S cm- 1 at room temperature and a low activation energy of 12 kJ mol- 1 [Mizuno et al., Solid State Ionics, vol. 177 (2006) 2721]. The crystal structure was solved by a direct space global optimization technique and refined by the Rietveld method. The compound crystallizes in a triclinic cell, space group P-1, a = 12.5009(3) Å, b = 6.03160(17) Å, c = 12.5303(3) Å, α = 102.845(3)°, β = 113.2024(18)°, γ = 74.467(3)°. PS4 tetrahedra and P2S7 ditetrahedra are contained in the structure and Li ions are situated between them. © 2007 Elsevier B.V. All rights reserved. | Source Title: | Solid State Ionics | URI: | http://scholarbank.nus.edu.sg/handle/10635/86243 | ISSN: | 01672738 | DOI: | 10.1016/j.ssi.2007.05.020 |
| Appears in Collections: | Staff Publications |
Show full item record
Files in This Item:
There are no files associated with this item.
SCOPUSTM
Citations
129
checked on Apr 22, 2019
WEB OF SCIENCETM
Citations
117
checked on Apr 22, 2019
Page view(s)
167
checked on Apr 21, 2019
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.