Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.electacta.2011.11.118
DC FieldValue
dc.titleA reliable TiO 2 nanotube membrane transfer method and its application in photovoltaic devices
dc.contributor.authorLi, K.-L.
dc.contributor.authorXie, Z.-B.
dc.contributor.authorAdams, S.
dc.date.accessioned2014-10-07T09:47:39Z
dc.date.available2014-10-07T09:47:39Z
dc.date.issued2012-02-15
dc.identifier.citationLi, K.-L., Xie, Z.-B., Adams, S. (2012-02-15). A reliable TiO 2 nanotube membrane transfer method and its application in photovoltaic devices. Electrochimica Acta 62 : 116-123. ScholarBank@NUS Repository. https://doi.org/10.1016/j.electacta.2011.11.118
dc.identifier.issn00134686
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/86178
dc.description.abstractIn this work we present a highly reproducible method to fabricate front-illuminated TiO 2 nanotube-based dye-sensitized solar-cell. The well oriented nature of the nanotube arrays ensures favorable electron percolation pathways for charge transfer between interfaces. Our two-step anodization approach allows for a nearly 100% reliable production of uniform films with a greater flexibility in the thickness of the nanotube membranes suitable for both liquid and solid electrolyte dye-sensitized solar-cells (DSCs). Large area nanotube membranes fabricated by this method were successfully detached and transferred onto fluorine-doped tin oxide (FTO) and other substrates without crack formation. In contrast to earlier methods, the method presented here does not require steps that may damage the nanotube membrane quality such as prolonged ultrasonication or acid treatment. We systematically study the current-time profile and analyze the detachment mechanism. Front-illuminated nanotube-based dye-sensitized solar-cells using this method reach an efficiency of 6.3% with liquid electrolytes (of which at least 6.1% originate from the transferred membrane) and 1.9% when using the solid state hole conductor CuSCN under AM1.5 1 sun illumination. © 2011 Elsevier Ltd.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.electacta.2011.11.118
dc.sourceScopus
dc.subjectElectrochemical impedance spectroscopy
dc.subjectMembrane transfer
dc.subjectPhotovoltaics
dc.subjectSolid-state dye-sensitized heterojunction cell
dc.subjectTitania nanotube membrane
dc.typeArticle
dc.contributor.departmentMATERIALS SCIENCE AND ENGINEERING
dc.description.doi10.1016/j.electacta.2011.11.118
dc.description.sourcetitleElectrochimica Acta
dc.description.volume62
dc.description.page116-123
dc.description.codenELCAA
dc.identifier.isiut000301096100016
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