Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201200210
Title: Redox-active metal-centered oxalato phosphate open framework cathode materials for lithium ion batteries
Authors: Nagarathinam, M. 
Saravanan, K. 
Phua, E.J.H.
Reddy, M.V. 
Chowdari, B.V.R. 
Vittal, J.J. 
Keywords: cyclic voltammetry
electrochemistry
lithium
redox chemistry
X-ray diffraction
Issue Date: 11-Jun-2012
Citation: Nagarathinam, M., Saravanan, K., Phua, E.J.H., Reddy, M.V., Chowdari, B.V.R., Vittal, J.J. (2012-06-11). Redox-active metal-centered oxalato phosphate open framework cathode materials for lithium ion batteries. Angewandte Chemie - International Edition 51 (24) : 5866-5870. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201200210
Abstract: MOP(OF) up the lithium: Metal organic-phosphate open framework materials, for example K 2.5[(VO) 2(HPO 4) 1.5(PO 4) 0.5(C 2O 4)] (see scheme), are investigated as hybrid cathode materials for lithium ion batteries. The redox-active metal center, robustness, available two-dimensional migration pathways in the abplane, and cavities along the caxis for the migration of the alkali metal ions allow the rapid insertion and extraction of alkali metal ions. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/85595
ISSN: 14337851
DOI: 10.1002/anie.201200210
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