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Please use this identifier to cite or link to this item: https://doi.org/10.1016/S1387-7003(03)00014-5
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dc.titleSynthesis and characterization of [Ga(TPP)H] (TPP = tetraphenylporphyrinato)
dc.contributor.authorFeng, Y.
dc.contributor.authorOng, S.-L.
dc.contributor.authorHu, J.
dc.contributor.authorNg, W.-J.
dc.date.accessioned2014-10-07T06:27:58Z
dc.date.available2014-10-07T06:27:58Z
dc.date.issued2003-05-01
dc.identifier.citationFeng, Y., Ong, S.-L., Hu, J., Ng, W.-J. (2003-05-01). Synthesis and characterization of [Ga(TPP)H] (TPP = tetraphenylporphyrinato). Inorganic Chemistry Communications 6 (5) : 466-468. ScholarBank@NUS Repository. https://doi.org/10.1016/S1387-7003(03)00014-5
dc.identifier.issn13877003
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/84680
dc.description.abstractThe synthesis, spectroscopic and structural characterization of the stable gallium hydride compound [Ga(TPP)H] (TPP = 5,10,15,20-tetraphenylporphyrinato) have been reported. The hydride compound was synthesized in high yield (85%) by reducing [Ga(TPP)Cl] with sodium borohydride in N,N-dimethylformamide. The title compound was fully characterized by spectroscopic methods (IR, UV-Vis, and 1H NMR spectroscopy) and its molecular structure was established by X-ray crystallography. The Ga-H IR stretch occurs at 1864 cm-1, and the hydride 1H NMR resonance locates at -6.47 ppm. The gallium-hydrogen distance is 1.48(4) Å, whereas the gallium atom lies 0.46(1) Å from the perfect porphyrin plane. © 2003 Elsevier Science B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S1387-7003(03)00014-5
dc.sourceScopus
dc.subjectCrystal structure
dc.subjectGallium
dc.subjectHydride
dc.subjectPorphyrin
dc.typeArticle
dc.contributor.departmentCIVIL ENGINEERING
dc.description.doi10.1016/S1387-7003(03)00014-5
dc.description.sourcetitleInorganic Chemistry Communications
dc.description.volume6
dc.description.issue5
dc.description.page466-468
dc.description.codenICCOF
dc.identifier.isiut000181871300010
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