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https://doi.org/10.1016/S1387-7003(03)00014-5
DC Field | Value | |
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dc.title | Synthesis and characterization of [Ga(TPP)H] (TPP = tetraphenylporphyrinato) | |
dc.contributor.author | Feng, Y. | |
dc.contributor.author | Ong, S.-L. | |
dc.contributor.author | Hu, J. | |
dc.contributor.author | Ng, W.-J. | |
dc.date.accessioned | 2014-10-07T06:27:58Z | |
dc.date.available | 2014-10-07T06:27:58Z | |
dc.date.issued | 2003-05-01 | |
dc.identifier.citation | Feng, Y., Ong, S.-L., Hu, J., Ng, W.-J. (2003-05-01). Synthesis and characterization of [Ga(TPP)H] (TPP = tetraphenylporphyrinato). Inorganic Chemistry Communications 6 (5) : 466-468. ScholarBank@NUS Repository. https://doi.org/10.1016/S1387-7003(03)00014-5 | |
dc.identifier.issn | 13877003 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/84680 | |
dc.description.abstract | The synthesis, spectroscopic and structural characterization of the stable gallium hydride compound [Ga(TPP)H] (TPP = 5,10,15,20-tetraphenylporphyrinato) have been reported. The hydride compound was synthesized in high yield (85%) by reducing [Ga(TPP)Cl] with sodium borohydride in N,N-dimethylformamide. The title compound was fully characterized by spectroscopic methods (IR, UV-Vis, and 1H NMR spectroscopy) and its molecular structure was established by X-ray crystallography. The Ga-H IR stretch occurs at 1864 cm-1, and the hydride 1H NMR resonance locates at -6.47 ppm. The gallium-hydrogen distance is 1.48(4) Å, whereas the gallium atom lies 0.46(1) Å from the perfect porphyrin plane. © 2003 Elsevier Science B.V. All rights reserved. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S1387-7003(03)00014-5 | |
dc.source | Scopus | |
dc.subject | Crystal structure | |
dc.subject | Gallium | |
dc.subject | Hydride | |
dc.subject | Porphyrin | |
dc.type | Article | |
dc.contributor.department | CIVIL ENGINEERING | |
dc.description.doi | 10.1016/S1387-7003(03)00014-5 | |
dc.description.sourcetitle | Inorganic Chemistry Communications | |
dc.description.volume | 6 | |
dc.description.issue | 5 | |
dc.description.page | 466-468 | |
dc.description.coden | ICCOF | |
dc.identifier.isiut | 000181871300010 | |
Appears in Collections: | Staff Publications |
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