Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/77141
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dc.titleSynthesis and characterization of oligothiophene-modified spirobifluorene
dc.contributor.authorPei, J.
dc.contributor.authorLiu, B.
dc.contributor.authorNi, J.
dc.contributor.authorZhou, X.-H.
dc.date.accessioned2014-06-23T05:51:24Z
dc.date.available2014-06-23T05:51:24Z
dc.date.issued2001
dc.identifier.citationPei, J.,Liu, B.,Ni, J.,Zhou, X.-H. (2001). Synthesis and characterization of oligothiophene-modified spirobifluorene. Acta Chimica Sinica 59 (10) : 1712-1721. ScholarBank@NUS Repository.
dc.identifier.issn05677351
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/77141
dc.description.abstractA series of novel 9,9′-spirobifluorenes functionalized by non-substituted oligothiophenes were synthesized through a coupling reaction between the oligothienyl-zinc chloride and the brominated spirobifluorene. The core is a 9,9′-spirobifiuorene and all the branching arms are affixed to the core in a single operation, which makes the syntheses highly convergent. The tetrahedral bonding atom at the center of a spiro-annulated molecule maintains 90° angle between the connected conjugated moieties via a σ-bonded network, which is useful to modify the steric demand of small molecular compounds to improve their processibility and morphologic stability, with their electronic properties maintained. Contrary to the non-substituted α-oligo-thiophenes, which naturally intend to crystallize, the oligothiophene modified 9,9′-spirobifluorenes were found to readily form amorphous glasses at ambient temperature and to exhibit high morphological stability with high glass transition temperatures ranging from 101°C to 186°C. This series of materials also kept the good properties of oligothiophenes, such as the easy accessibility through various synthetic methodologies, good chemical and thermal stability, as well as the tunable energy levels and the emission color.
dc.sourceScopus
dc.subject9,9′-spirobifluorene
dc.subjectOligothiophenes
dc.subjectOptical materials
dc.subjectSynthesis
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleActa Chimica Sinica
dc.description.volume59
dc.description.issue10
dc.description.page1712-1721
dc.identifier.isiutNOT_IN_WOS
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