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Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/76482
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dc.titleMetalloporphyrin-catalyzed hydroxylation of cyclohexane with molecular oxygen
dc.contributor.authorJi, L.-N.
dc.contributor.authorLiu, M.
dc.contributor.authorHsieh, A.-K.
dc.contributor.authorHor, T.S.A.
dc.date.accessioned2014-06-23T05:43:20Z
dc.date.available2014-06-23T05:43:20Z
dc.date.issued1991-12-01
dc.identifier.citationJi, L.-N.,Liu, M.,Hsieh, A.-K.,Hor, T.S.A. (1991-12-01). Metalloporphyrin-catalyzed hydroxylation of cyclohexane with molecular oxygen. Journal of Molecular Catalysis 70 (2) : 247-257. ScholarBank@NUS Repository.
dc.identifier.issn03045102
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/76482
dc.description.abstractThe selective oxidation of cyclohexane to cyclohexanol and cyclohexanone was realized in the model system of cytochromes P-450 consisting of chlorotetraphenylporphyrinato-Mn(III), Fe(III) or Co(II) complexes, molecular oxygen and ascorbic acid as coreductant. The catalytic efficiency was found to be sensitive to the peripheral phenyl substitution pattern of the porphyrinato ring in the complexes. The effects of the metal centre, axial ligand [substrate]/[catalyst] ratio and pH of mixture were examined and discussed with reference to oxidation mechanism. © 1991.
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleJournal of Molecular Catalysis
dc.description.volume70
dc.description.issue2
dc.description.page247-257
dc.identifier.isiutNOT_IN_WOS
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