Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/76473
DC Field | Value | |
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dc.title | Mercuricyclisation of D-erythro-hept-1,3-dienitol: Reductive demercuriation in the presence and absence of oxygen | |
dc.contributor.author | Lee, C.K. | |
dc.contributor.author | Jiang, H. | |
dc.date.accessioned | 2014-06-23T05:43:14Z | |
dc.date.available | 2014-06-23T05:43:14Z | |
dc.date.issued | 1999 | |
dc.identifier.citation | Lee, C.K.,Jiang, H. (1999). Mercuricyclisation of D-erythro-hept-1,3-dienitol: Reductive demercuriation in the presence and absence of oxygen. Carbohydrate Letters 3 (5) : 309-315. ScholarBank@NUS Repository. | |
dc.identifier.issn | 10735070 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/76473 | |
dc.description.abstract | Treatment of 3,5,7-tri-O-benzyl-D-erythro-hept-1,3-dienitol with mercuric acetate or trifluoromethanesulfonate followed by aqueous potassium chloride, produced (1,3,5-tri-O-benzyl-2-deoxy-2-chloromercurio-β-D- arabinofuranosyl)ethene (2) as the only isolated product. Reductive demercuriation of the chloromercurio-ether 2 in the presence of molecular oxygen gave a mixture of 3,7-dibenzyloxy-hept-1,3,5-triene-6-ol (3), (1,3,5- tri-O-benzyl-β-D-arabinofuranosyl)ethene (4) and D-ribofuranosyl)ethene (5). Compound 3 was obtained as the major product when the reaction was conducted at room temperature. At 0 °C, the reaction gave a 3:1 mixture of 4 and 5, with 3 being formed in only minor amounts. | |
dc.source | Scopus | |
dc.subject | (1,3,5-tri-O-benzyl-β-D-arabino- and ribo- furanosyl)ethene | |
dc.subject | 3,7-dibenzyloxy-hept-1,3,5-triene-6- ol | |
dc.subject | Borohydride-induced oxidation | |
dc.subject | D-erythro-hept-1,3-dienitol | |
dc.subject | Mercuri- cyclisation | |
dc.subject | Oxymercuriation-demercuriation | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Carbohydrate Letters | |
dc.description.volume | 3 | |
dc.description.issue | 5 | |
dc.description.page | 309-315 | |
dc.description.coden | CLETE | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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