Clay montmorillonite K10 catalyzed aldol-type reaction of aldehydes with silyl enol ethers in water

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0040-4020(99)00594-3

Title:	Clay montmorillonite K10 catalyzed aldol-type reaction of aldehydes with silyl enol ethers in water
Authors:	Loh, T.-P. Li, X.-R.
Keywords:	Aldehydes Aldol Reactions Clays Environmentally Friendly Water
Issue Date:	27-Aug-1999
Citation:	Loh, T.-P., Li, X.-R. (1999-08-27). Clay montmorillonite K10 catalyzed aldol-type reaction of aldehydes with silyl enol ethers in water. Tetrahedron 55 (35) : 10789-10802. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4020(99)00594-3
Abstract:	An environmentally friendly method for the cross aldol reaction of silyl enol ethers and ketene silyl acetal with various aldehydes using montmorillonite K10 is described. Cheap and commercially available montmorillonite K10 can be used without the need of an ion exchange process under solvent-free conditions or in water. Hydrate of aldehydes such as glyoxylic acid can be used directly. Thermal treatment of K10 increased the catalytic activity. The catalytic activity was supposed due to the properties of the structure of K10 and its inherent Bronsted acidity.
Source Title:	Tetrahedron
URI:	http://scholarbank.nus.edu.sg/handle/10635/75761
ISSN:	00404020
DOI:	10.1016/S0040-4020(99)00594-3
Appears in Collections:	Staff Publications

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