Please use this identifier to cite or link to this item:
|Title:||A general phase transfer protocol for synthesizing alkylamine-stabilized nanoparticles of noble metals||Authors:||Yang, J.
Noble metal nanoparticles
|Issue Date:||2007||Citation:||Yang, J., Lee, J.Y., Too, H.-P. (2007). A general phase transfer protocol for synthesizing alkylamine-stabilized nanoparticles of noble metals. Analytica Chimica Acta 588 (1) : 34-41. ScholarBank@NUS Repository. https://doi.org/10.1016/j.aca.2007.01.061||Abstract:||The ethanol-mediated phase transfer protocol was extended herein to prepare alkylamine-stabilized nanoparticles of several noble metals by transferring them from aqueous environment into toluene. This method relies on the use of ethanol as a mediator to provide and maintain adequate contact between dodecylamine and metal nanoparticles during the transfer process and involves first mixing the metal hydrosols and an ethanol solution of dodecylamine and then extracting the dodecylamine-stabilized metal nanoparticles into toluene. Alkylamine-stabilized Ag, Pd, Rh, Ir and Os nanoparticles with 7.09, 3.45, 6.89, 2.42 and 4.52 nm in diameter, respectively, could be prepared this way. The self-assembly of dodecylamine-stabilized Ag and Rh nanoparticles was also detected by transmission electron microscopy (TEM). © 2007 Elsevier B.V. All rights reserved.||Source Title:||Analytica Chimica Acta||URI:||http://scholarbank.nus.edu.sg/handle/10635/28786||ISSN:||00032670||DOI:||10.1016/j.aca.2007.01.061|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on May 20, 2019
WEB OF SCIENCETM
checked on May 13, 2019
checked on May 12, 2019
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.