Please use this identifier to cite or link to this item:
https://doi.org/10.1002/chem.201606029
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dc.title | Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy-III Single-Ion Magnet | |
dc.contributor.author | Chen, Yan-Cong | |
dc.contributor.author | Liu, Jun-Liang | |
dc.contributor.author | Lan, Yanhua | |
dc.contributor.author | Zhong, Zhi-Qiang | |
dc.contributor.author | Mansikkamaki, Akseli | |
dc.contributor.author | Ungur, Liviu | |
dc.contributor.author | Li, Quan-Wen | |
dc.contributor.author | Jia, Jian-Hua | |
dc.contributor.author | Chibotaru, Liviu F | |
dc.contributor.author | Han, Jun-Bo | |
dc.contributor.author | Wernsdorfer, Wolfgang | |
dc.contributor.author | Chen, Xiao-Ming | |
dc.contributor.author | Tong, Ming-Liang | |
dc.date.accessioned | 2022-07-19T01:56:07Z | |
dc.date.available | 2022-07-19T01:56:07Z | |
dc.date.issued | 2017-04-27 | |
dc.identifier.citation | Chen, Yan-Cong, Liu, Jun-Liang, Lan, Yanhua, Zhong, Zhi-Qiang, Mansikkamaki, Akseli, Ungur, Liviu, Li, Quan-Wen, Jia, Jian-Hua, Chibotaru, Liviu F, Han, Jun-Bo, Wernsdorfer, Wolfgang, Chen, Xiao-Ming, Tong, Ming-Liang (2017-04-27). Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy-III Single-Ion Magnet. CHEMISTRY-A EUROPEAN JOURNAL 23 (24) : 5708-5715. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201606029 | |
dc.identifier.issn | 0947-6539 | |
dc.identifier.issn | 1521-3765 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/228800 | |
dc.description.abstract | The pentagonal bipyramidal single-ion magnets (SIMs) are among the most attractive prototypes of high-performance single-molecule magnets (SMMs). Here, a fluorescence-active phosphine oxide ligand CyPh2PO (=cyclohexyl(diphenyl)phosphine oxide) was introduced into [Dy(CyPh2PO)2(H2O)5]Br3⋅2 (CyPh2PO)⋅EtOH⋅3 H2O, and combined dynamic magnetic measurement, optical characterization, ab initio calculation, and magneto-optical correlation of this high-performance pseudo-D5h DyIII SIM with large Ueff (508(2) K) and high magnetic hysteresis temperature (19 K) were performed. This work provides a deeper insight into the rational design of promising molecular magnets. | |
dc.language.iso | en | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Multidisciplinary | |
dc.subject | Chemistry | |
dc.subject | dysprosium | |
dc.subject | fluorescence | |
dc.subject | lanthanide | |
dc.subject | magnetic properties | |
dc.subject | single-molecule magnets | |
dc.subject | MOLECULE-MAGNET | |
dc.subject | LANTHANIDE COMPLEXES | |
dc.subject | ANISOTROPY BARRIER | |
dc.subject | LOW-SYMMETRY | |
dc.subject | BLOCKING | |
dc.subject | RELAXATION | |
dc.subject | RATIONALIZATION | |
dc.subject | EXCHANGE | |
dc.subject | FIELD | |
dc.type | Article | |
dc.date.updated | 2022-07-15T02:48:01Z | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1002/chem.201606029 | |
dc.description.sourcetitle | CHEMISTRY-A EUROPEAN JOURNAL | |
dc.description.volume | 23 | |
dc.description.issue | 24 | |
dc.description.page | 5708-5715 | |
dc.published.state | Published | |
Appears in Collections: | Staff Publications Elements |
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Files in This Item:
File | Description | Size | Format | Access Settings | Version | |
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Chen_CEJ_2017.cif.txt | Supporting information | 48.74 kB | Text | CLOSED | None | |
Chen_CEJ_2017_SI.pdf | Supporting information | 1.67 MB | Adobe PDF | CLOSED | None | |
Chen_CEJ_2017.pdf | Published version | 2.26 MB | Adobe PDF | CLOSED | None |
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