Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.201606029
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dc.titleDynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy-III Single-Ion Magnet
dc.contributor.authorChen, Yan-Cong
dc.contributor.authorLiu, Jun-Liang
dc.contributor.authorLan, Yanhua
dc.contributor.authorZhong, Zhi-Qiang
dc.contributor.authorMansikkamaki, Akseli
dc.contributor.authorUngur, Liviu
dc.contributor.authorLi, Quan-Wen
dc.contributor.authorJia, Jian-Hua
dc.contributor.authorChibotaru, Liviu F
dc.contributor.authorHan, Jun-Bo
dc.contributor.authorWernsdorfer, Wolfgang
dc.contributor.authorChen, Xiao-Ming
dc.contributor.authorTong, Ming-Liang
dc.date.accessioned2022-07-19T01:56:07Z
dc.date.available2022-07-19T01:56:07Z
dc.date.issued2017-04-27
dc.identifier.citationChen, Yan-Cong, Liu, Jun-Liang, Lan, Yanhua, Zhong, Zhi-Qiang, Mansikkamaki, Akseli, Ungur, Liviu, Li, Quan-Wen, Jia, Jian-Hua, Chibotaru, Liviu F, Han, Jun-Bo, Wernsdorfer, Wolfgang, Chen, Xiao-Ming, Tong, Ming-Liang (2017-04-27). Dynamic Magnetic and Optical Insight into a High Performance Pentagonal Bipyramidal Dy-III Single-Ion Magnet. CHEMISTRY-A EUROPEAN JOURNAL 23 (24) : 5708-5715. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201606029
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228800
dc.description.abstractThe pentagonal bipyramidal single-ion magnets (SIMs) are among the most attractive prototypes of high-performance single-molecule magnets (SMMs). Here, a fluorescence-active phosphine oxide ligand CyPh2PO (=cyclohexyl(diphenyl)phosphine oxide) was introduced into [Dy(CyPh2PO)2(H2O)5]Br3⋅2 (CyPh2PO)⋅EtOH⋅3 H2O, and combined dynamic magnetic measurement, optical characterization, ab initio calculation, and magneto-optical correlation of this high-performance pseudo-D5h DyIII SIM with large Ueff (508(2) K) and high magnetic hysteresis temperature (19 K) were performed. This work provides a deeper insight into the rational design of promising molecular magnets.
dc.language.isoen
dc.publisherWILEY-V C H VERLAG GMBH
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectdysprosium
dc.subjectfluorescence
dc.subjectlanthanide
dc.subjectmagnetic properties
dc.subjectsingle-molecule magnets
dc.subjectMOLECULE-MAGNET
dc.subjectLANTHANIDE COMPLEXES
dc.subjectANISOTROPY BARRIER
dc.subjectLOW-SYMMETRY
dc.subjectBLOCKING
dc.subjectRELAXATION
dc.subjectRATIONALIZATION
dc.subjectEXCHANGE
dc.subjectFIELD
dc.typeArticle
dc.date.updated2022-07-15T02:48:01Z
dc.contributor.departmentDEPT OF CHEMISTRY
dc.description.doi10.1002/chem.201606029
dc.description.sourcetitleCHEMISTRY-A EUROPEAN JOURNAL
dc.description.volume23
dc.description.issue24
dc.description.page5708-5715
dc.published.statePublished
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