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Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201202497
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dc.titleA High Anisotropy Barrier in a Sulfur-Bridged Organodysprosium Single-Molecule Magnet
dc.contributor.authorTuna, Floriana
dc.contributor.authorSmith, Charlene A
dc.contributor.authorBodensteiner, Michael
dc.contributor.authorUngur, Liviu
dc.contributor.authorChibotaru, Liviu F
dc.contributor.authorMcInnes, Eric JL
dc.contributor.authorWinpenny, Richard EP
dc.contributor.authorCollison, David
dc.contributor.authorLayfield, Richard A
dc.date.accessioned2022-07-18T08:31:32Z
dc.date.available2022-07-18T08:31:32Z
dc.date.issued2012-01-01
dc.identifier.citationTuna, Floriana, Smith, Charlene A, Bodensteiner, Michael, Ungur, Liviu, Chibotaru, Liviu F, McInnes, Eric JL, Winpenny, Richard EP, Collison, David, Layfield, Richard A (2012-01-01). A High Anisotropy Barrier in a Sulfur-Bridged Organodysprosium Single-Molecule Magnet. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 51 (28) : 6976-6980. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201202497
dc.identifier.issn14337851
dc.identifier.issn15213773
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228784
dc.description.abstractThe sulfur-bridged dimers [{Cp'2Ln(μ-SSiPh3)} 2] (Ln=Gd (1), Dy (2); Cp'=η5-C 5H4Me) were synthesized by the transmetalation reactions between [Cp'3Ln] and Ph3SiSLi. Compound 2 is a single-molecule magnet with slow relaxation of magnetization up to 40 K and an anisotropy barrier of Ueff=133 cm-1. Insight into the SMM properties of 2 and closely related SMMs has been obtained using ab initio calculations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.language.isoen
dc.publisherWILEY-V C H VERLAG GMBH
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectab initio calculations
dc.subjectdysprosium
dc.subjectorganometallics
dc.subjectsingle-molecule magnets
dc.subjectsulfur
dc.subjectDYSPROSIUM TRIANGLES
dc.subjectION MAGNET
dc.subjectRELAXATION
dc.subjectBEHAVIOR
dc.subjectCOMPLEX
dc.subjectEXCHANGE
dc.subjectMAGNETIZATION
dc.subjectBISTABILITY
dc.subjectAXIALITY
dc.subjectSURFACE
dc.typeArticle
dc.date.updated2022-07-15T01:26:25Z
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/anie.201202497
dc.description.sourcetitleANGEWANDTE CHEMIE-INTERNATIONAL EDITION
dc.description.volume51
dc.description.issue28
dc.description.page6976-6980
dc.published.statePublished
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