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Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201201478
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dc.titleCoexistence of Distinct Single-Ion and Exchange-Based Mechanisms for Blocking of Magnetization in a CoII2DyIII2 Single-Molecule Magnet
dc.contributor.authorMondal, Kartik Chandra
dc.contributor.authorSundt, Alexander
dc.contributor.authorLan, Yanhua
dc.contributor.authorKostakis, George E
dc.contributor.authorWaldmann, Oliver
dc.contributor.authorUngur, Liviu
dc.contributor.authorChibotaru, Liviu F
dc.contributor.authorAnson, Christopher E
dc.contributor.authorPowell, Annie K
dc.date.accessioned2022-07-18T06:52:38Z
dc.date.available2022-07-18T06:52:38Z
dc.date.issued2012-01-01
dc.identifier.citationMondal, Kartik Chandra, Sundt, Alexander, Lan, Yanhua, Kostakis, George E, Waldmann, Oliver, Ungur, Liviu, Chibotaru, Liviu F, Anson, Christopher E, Powell, Annie K (2012-01-01). Coexistence of Distinct Single-Ion and Exchange-Based Mechanisms for Blocking of Magnetization in a CoII2DyIII2 Single-Molecule Magnet. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 51 (30) : 7550-7554. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201201478
dc.identifier.issn14337851
dc.identifier.issn15213773
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228763
dc.description.abstractTwo ways to relax: A defect-dicubane Co 2Dy 2 single-molecule magnet (SMM) displays slow relaxation of magnetization with a blocking temperature of 22 K (at 1500 Hz), the highest reported for a 3d-4f-based SMM. Analysis of the relaxation reveals two distinct blocking regimes, one of which is intraionic, localized on the Dy III ions, while the other is exchange-based. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
dc.language.isoen
dc.publisherWILEY-V C H VERLAG GMBH
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectab initio calculations
dc.subjectcobalt
dc.subjecthigh-energy barriers
dc.subjectlanthanides
dc.subjectsingle-molecule magnets
dc.subjectSUSCEPTIBILITY
dc.subjectCOMPLEXES
dc.subjectSTATE
dc.subjectLH3
dc.subjectDY
dc.subjectLN
dc.typeArticle
dc.date.updated2022-07-15T01:27:27Z
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/anie.201201478
dc.description.sourcetitleANGEWANDTE CHEMIE-INTERNATIONAL EDITION
dc.description.volume51
dc.description.issue30
dc.description.page7550-7554
dc.published.statePublished
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