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https://doi.org/10.1039/c5dt04072h
| Title: | Observation of unusual slow-relaxation of the magnetisation in a Gd-EDTA chelate | Authors: | Holmberg, Rebecca J Le, Tuan Anh Ho Ungur, Liviu Korobkov, Ilia Chibotaru, Liviu F Murugesu, Muralee |
Keywords: | Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry MRI CONTRAST AGENTS CENTER-DOT 5H(2)O COMPLEXES 8-COORDINATE PENTAHYDRATE 9-COORDINATE GADOLINIUM CRYSTAL |
Issue Date: | 1-Jan-2015 | Publisher: | ROYAL SOC CHEMISTRY | Citation: | Holmberg, Rebecca J, Le, Tuan Anh Ho, Ungur, Liviu, Korobkov, Ilia, Chibotaru, Liviu F, Murugesu, Muralee (2015-01-01). Observation of unusual slow-relaxation of the magnetisation in a Gd-EDTA chelate. DALTON TRANSACTIONS 44 (47) : 20321-20325. ScholarBank@NUS Repository. https://doi.org/10.1039/c5dt04072h | Abstract: | A Gadolinium EDTA chelate displays characteristic isotropic behaviour common of GdIII complexes under zero applied magnetic field, and anisotropic behaviour arising from dipolar coupling and weak spin-phonon coupling under an applied magnetic field. This surprising magnetic behaviour for GdIII is investigated using SQUID magnetometry and rationalized through theoretical calculations. | Source Title: | DALTON TRANSACTIONS | URI: | https://scholarbank.nus.edu.sg/handle/10635/228718 | ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/c5dt04072h |
| Appears in Collections: | Staff Publications Elements |
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| File | Description | Size | Format | Access Settings | Version | |
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| Holmberg_DT_2015.cif.txt | Supporting information | 44 kB | Text | CLOSED | None | |
| Holmberg_DT_2015.pdf | Published version | 1.21 MB | Adobe PDF | CLOSED | None | |
| Holmberg_DT_2015_SI.pdf | Supporting information | 1.87 MB | Adobe PDF | CLOSED | None |
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