Please use this identifier to cite or link to this item: https://doi.org/10.1021/ic502443g
DC FieldValue
dc.titleField-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment
dc.contributor.authorXue, Shufang
dc.contributor.authorUngur, Liviu
dc.contributor.authorGuo, Yun-Nan
dc.contributor.authorTang, Jinkui
dc.contributor.authorChibotaru, Liviu F
dc.date.accessioned2022-07-16T14:49:53Z
dc.date.available2022-07-16T14:49:53Z
dc.date.issued2014-12-01
dc.identifier.citationXue, Shufang, Ungur, Liviu, Guo, Yun-Nan, Tang, Jinkui, Chibotaru, Liviu F (2014-12-01). Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment. INORGANIC CHEMISTRY 53 (23) : 12658-12663. ScholarBank@NUS Repository. https://doi.org/10.1021/ic502443g
dc.identifier.issn0020-1669
dc.identifier.issn1520-510X
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228717
dc.description.abstractA defective cubane-shaped heterometallic trinuclear CoIII2DyIII compound with only one magnetically interesting ion (DyIII) has been assembled by virtue of a multifunctional acylhydrazone ligand. Because of the nonaxial ground state of DyIII ion derived from a low-symmetrical crystal field, the title compound displays field-induced multiple relaxation processes which are of molecular and a dipolar-dipolar coupling origin, as revealed by combined experimental and theoretical investigations. The results demonstrate that such a mononuclear dysprosium(III) compound with a low-symmetrical environment of magnetic center appears to be a model system for further investigations to shed light on the complex relaxation mechanism of lanthanide-based single ion magnets.
dc.language.isoen
dc.publisherAMER CHEMICAL SOC
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Inorganic & Nuclear
dc.subjectChemistry
dc.subjectSINGLE-MOLECULE-MAGNET
dc.subjectPOLYHEDRAL STRUCTURES
dc.subjectANISOTROPY BARRIER
dc.subjectODD NUMBER
dc.subjectSUBSTITUTION
dc.subjectCOMPLEXES
dc.subjectBLOCKING
dc.subjectVERTICES
dc.typeArticle
dc.date.updated2022-07-15T02:20:30Z
dc.contributor.departmentDEPT OF CHEMISTRY
dc.description.doi10.1021/ic502443g
dc.description.sourcetitleINORGANIC CHEMISTRY
dc.description.volume53
dc.description.issue23
dc.description.page12658-12663
dc.published.statePublished
Appears in Collections:Elements
Staff Publications

Show simple item record
Files in This Item:
File Description SizeFormatAccess SettingsVersion 
Xue_IC_2014.pdfPublished version384.28 kBAdobe PDF

CLOSED

None
Xue_IC_2014.cif.txtSupporting information55.71 kBText

CLOSED

None
Xue_IC_2014_SI.pdfSupporting information904.28 kBAdobe PDF

CLOSED

None

SCOPUSTM   
Citations

39
checked on Jan 26, 2023

Page view(s)

50
checked on Jan 26, 2023

Download(s)

2
checked on Jan 26, 2023

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.