Please use this identifier to cite or link to this item:
https://doi.org/10.1021/ic502443g
DC Field | Value | |
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dc.title | Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment | |
dc.contributor.author | Xue, Shufang | |
dc.contributor.author | Ungur, Liviu | |
dc.contributor.author | Guo, Yun-Nan | |
dc.contributor.author | Tang, Jinkui | |
dc.contributor.author | Chibotaru, Liviu F | |
dc.date.accessioned | 2022-07-16T14:49:53Z | |
dc.date.available | 2022-07-16T14:49:53Z | |
dc.date.issued | 2014-12-01 | |
dc.identifier.citation | Xue, Shufang, Ungur, Liviu, Guo, Yun-Nan, Tang, Jinkui, Chibotaru, Liviu F (2014-12-01). Field-Induced Multiple Relaxation Mechanism of (Co2DyIII)-Dy-III Compound with the Dysprosium Ion in a Low-Symmetrical Environment. INORGANIC CHEMISTRY 53 (23) : 12658-12663. ScholarBank@NUS Repository. https://doi.org/10.1021/ic502443g | |
dc.identifier.issn | 0020-1669 | |
dc.identifier.issn | 1520-510X | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/228717 | |
dc.description.abstract | A defective cubane-shaped heterometallic trinuclear CoIII2DyIII compound with only one magnetically interesting ion (DyIII) has been assembled by virtue of a multifunctional acylhydrazone ligand. Because of the nonaxial ground state of DyIII ion derived from a low-symmetrical crystal field, the title compound displays field-induced multiple relaxation processes which are of molecular and a dipolar-dipolar coupling origin, as revealed by combined experimental and theoretical investigations. The results demonstrate that such a mononuclear dysprosium(III) compound with a low-symmetrical environment of magnetic center appears to be a model system for further investigations to shed light on the complex relaxation mechanism of lanthanide-based single ion magnets. | |
dc.language.iso | en | |
dc.publisher | AMER CHEMICAL SOC | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | Chemistry | |
dc.subject | SINGLE-MOLECULE-MAGNET | |
dc.subject | POLYHEDRAL STRUCTURES | |
dc.subject | ANISOTROPY BARRIER | |
dc.subject | ODD NUMBER | |
dc.subject | SUBSTITUTION | |
dc.subject | COMPLEXES | |
dc.subject | BLOCKING | |
dc.subject | VERTICES | |
dc.type | Article | |
dc.date.updated | 2022-07-15T02:20:30Z | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1021/ic502443g | |
dc.description.sourcetitle | INORGANIC CHEMISTRY | |
dc.description.volume | 53 | |
dc.description.issue | 23 | |
dc.description.page | 12658-12663 | |
dc.published.state | Published | |
Appears in Collections: | Elements Staff Publications |
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Files in This Item:
File | Description | Size | Format | Access Settings | Version | |
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Xue_IC_2014.pdf | Published version | 384.28 kB | Adobe PDF | CLOSED | None | |
Xue_IC_2014.cif.txt | Supporting information | 55.71 kB | Text | CLOSED | None | |
Xue_IC_2014_SI.pdf | Supporting information | 904.28 kB | Adobe PDF | CLOSED | None |
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