1. ScholarBank@NUS
  2. 1. Staff
  3. Elements
Please use this identifier to cite or link to this item: https://doi.org/10.1039/c7sc04873d
DC FieldValue
dc.titleExchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes
dc.contributor.authorZhang, Peng
dc.contributor.authorPerfetti, Mauro
dc.contributor.authorKern, Michal
dc.contributor.authorHallmen, Philipp P
dc.contributor.authorUngur, Liviu
dc.contributor.authorLenz, Samuel
dc.contributor.authorRingenberg, Mark R
dc.contributor.authorFrey, Wolfgang
dc.contributor.authorStoll, Hermann
dc.contributor.authorRauhut, Guntram
dc.contributor.authorvan Slageren, Joris
dc.date.accessioned2022-07-15T08:26:40Z
dc.date.available2022-07-15T08:26:40Z
dc.date.issued2018-02-07
dc.identifier.citationZhang, Peng, Perfetti, Mauro, Kern, Michal, Hallmen, Philipp P, Ungur, Liviu, Lenz, Samuel, Ringenberg, Mark R, Frey, Wolfgang, Stoll, Hermann, Rauhut, Guntram, van Slageren, Joris (2018-02-07). Exchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes. CHEMICAL SCIENCE 9 (5) : 1221-1230. ScholarBank@NUS Repository. https://doi.org/10.1039/c7sc04873d
dc.identifier.issn20416520
dc.identifier.issn20416539
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/228690
dc.description.abstractTetraoxolene radical-bridged lanthanide SMM systems were prepared for the first time by reduction of the respective neutral compounds. Magnetic measurements reveal the profound influence of the radical center on magnetic behavior. Strong magnetic couplings are revealed in the radical species, which switch on SMM behavior under zero applied field for DyIII and TbIII compounds. HFEPR spectra unravel the contributions of the magnetic coupling and the magnetic anisotropy. For GdIII this results in much more accurate magnetic coupling parameters with respect to bulk magnetic measurements.
dc.language.isoen
dc.publisherROYAL SOC CHEMISTRY
dc.sourceElements
dc.subjectScience & Technology
dc.subjectPhysical Sciences
dc.subjectChemistry, Multidisciplinary
dc.subjectChemistry
dc.subjectRARE-EARTH COMPLEXES
dc.subjectHIGH-FIELD EPR
dc.subjectSEMIQUINONATO COMPLEX
dc.subjectURANIUM(III) COMPLEXES
dc.subjectION MAGNET
dc.subjectRELAXATION
dc.subjectANISOTROPY
dc.subjectBLOCKING
dc.subjectBEHAVIOR
dc.subjectMAGNETIZATION
dc.typeArticle
dc.date.updated2022-07-15T02:52:24Z
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1039/c7sc04873d
dc.description.sourcetitleCHEMICAL SCIENCE
dc.description.volume9
dc.description.issue5
dc.description.page1221-1230
dc.published.statePublished
Appears in Collections:Elements
Staff Publications

Show simple item record
Files in This Item:
File Description SizeFormatAccess SettingsVersion 
Zhang_CS_2018.cif.txtSupporting information106.64 kBText

OPEN

NoneView/Download
Zhang_CS_2018.pdfPublished version1.22 MBAdobe PDF

OPEN

PublishedView/Download
Zhang_CS_2018_SI.pdfSupporting information2.8 MBAdobe PDF

OPEN

NoneView/Download

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.