Please use this identifier to cite or link to this item:
https://doi.org/10.1039/c7sc04873d
DC Field | Value | |
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dc.title | Exchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes | |
dc.contributor.author | Zhang, Peng | |
dc.contributor.author | Perfetti, Mauro | |
dc.contributor.author | Kern, Michal | |
dc.contributor.author | Hallmen, Philipp P | |
dc.contributor.author | Ungur, Liviu | |
dc.contributor.author | Lenz, Samuel | |
dc.contributor.author | Ringenberg, Mark R | |
dc.contributor.author | Frey, Wolfgang | |
dc.contributor.author | Stoll, Hermann | |
dc.contributor.author | Rauhut, Guntram | |
dc.contributor.author | van Slageren, Joris | |
dc.date.accessioned | 2022-07-15T08:26:40Z | |
dc.date.available | 2022-07-15T08:26:40Z | |
dc.date.issued | 2018-02-07 | |
dc.identifier.citation | Zhang, Peng, Perfetti, Mauro, Kern, Michal, Hallmen, Philipp P, Ungur, Liviu, Lenz, Samuel, Ringenberg, Mark R, Frey, Wolfgang, Stoll, Hermann, Rauhut, Guntram, van Slageren, Joris (2018-02-07). Exchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes. CHEMICAL SCIENCE 9 (5) : 1221-1230. ScholarBank@NUS Repository. https://doi.org/10.1039/c7sc04873d | |
dc.identifier.issn | 20416520 | |
dc.identifier.issn | 20416539 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/228690 | |
dc.description.abstract | Tetraoxolene radical-bridged lanthanide SMM systems were prepared for the first time by reduction of the respective neutral compounds. Magnetic measurements reveal the profound influence of the radical center on magnetic behavior. Strong magnetic couplings are revealed in the radical species, which switch on SMM behavior under zero applied field for DyIII and TbIII compounds. HFEPR spectra unravel the contributions of the magnetic coupling and the magnetic anisotropy. For GdIII this results in much more accurate magnetic coupling parameters with respect to bulk magnetic measurements. | |
dc.language.iso | en | |
dc.publisher | ROYAL SOC CHEMISTRY | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Multidisciplinary | |
dc.subject | Chemistry | |
dc.subject | RARE-EARTH COMPLEXES | |
dc.subject | HIGH-FIELD EPR | |
dc.subject | SEMIQUINONATO COMPLEX | |
dc.subject | URANIUM(III) COMPLEXES | |
dc.subject | ION MAGNET | |
dc.subject | RELAXATION | |
dc.subject | ANISOTROPY | |
dc.subject | BLOCKING | |
dc.subject | BEHAVIOR | |
dc.subject | MAGNETIZATION | |
dc.type | Article | |
dc.date.updated | 2022-07-15T02:52:24Z | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1039/c7sc04873d | |
dc.description.sourcetitle | CHEMICAL SCIENCE | |
dc.description.volume | 9 | |
dc.description.issue | 5 | |
dc.description.page | 1221-1230 | |
dc.published.state | Published | |
Appears in Collections: | Elements Staff Publications |
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Zhang_CS_2018.cif.txt | Supporting information | 106.64 kB | Text | OPEN | None | View/Download |
Zhang_CS_2018.pdf | Published version | 1.22 MB | Adobe PDF | OPEN | Published | View/Download |
Zhang_CS_2018_SI.pdf | Supporting information | 2.8 MB | Adobe PDF | OPEN | None | View/Download |
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