Bimetallic Nickel Cobalt Sulfide as Efficient Electrocatalyst for Zn–Air Battery and Water Splitting

Abstract

The development of efficient earth-abundant electrocatalysts for oxygen reduction, oxygen evolution, and hydrogen evolution reactions (ORR, OER, and HER) is important for future energy conversion and energy storage devices, for which both rechargeable Zn–air batteries and water splitting have raised great expectations. Herein, we report a single-phase bimetallic nickel cobalt sulfide ((Ni,Co)S 2 ) as an efficient electrocatalyst for both OER and ORR. Owing to the synergistic combination of Ni and Co, the (Ni,Co)S 2 exhibits superior electrocatalytic performance for ORR, OER, and HER in an alkaline electrolyte, and the first principle calculation results indicate that the reaction of an adsorbed O atom with a H 2 O molecule to form a *OOH is the potential limiting step in the OER. Importantly, it could be utilized as an advanced air electrode material in Zn–air batteries, which shows an enhanced charge–discharge performance (charging voltage of 1.71 V and discharge voltage of 1.26 V at 2 mA cm ?2 ), large specific capacity (842 mAh g Zn ?1 at 5 mA cm ?2 ), and excellent cycling stability (480 h). Interestingly, the (Ni,Co)S 2 -based Zn–air battery can efficiently power an electrochemical water-splitting unit with (Ni,Co)S 2 serving as both the electrodes. This reveals that the prepared (Ni,Co)S 2 has promising applications in future energy conversion and energy storage devices.[Figure not available: see fulltext.]. © 2019, © 2019, The Author(s).