Please use this identifier to cite or link to this item:
https://doi.org/10.1002/open.202000041
DC Field | Value | |
---|---|---|
dc.title | Interfacial Synthesis of a Monolayered Fluorescent Two-Dimensional Polymer through Dynamic Imine Chemistry | |
dc.contributor.author | Zhang, Z. | |
dc.contributor.author | Liu, H. | |
dc.contributor.author | Sun, Q. | |
dc.contributor.author | Shao, F. | |
dc.contributor.author | Pan, Q. | |
dc.contributor.author | Zhuang, T. | |
dc.contributor.author | Zhao, Y. | |
dc.date.accessioned | 2021-08-13T02:53:37Z | |
dc.date.available | 2021-08-13T02:53:37Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Zhang, Z., Liu, H., Sun, Q., Shao, F., Pan, Q., Zhuang, T., Zhao, Y. (2020). Interfacial Synthesis of a Monolayered Fluorescent Two-Dimensional Polymer through Dynamic Imine Chemistry. ChemistryOpen 9 (3) : 381-385. ScholarBank@NUS Repository. https://doi.org/10.1002/open.202000041 | |
dc.identifier.issn | 21911363 | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/196793 | |
dc.description.abstract | A fluorescent monolayered two-dimensional polymer (2DP) containing both tetraphenylethylene (TPE) and imine linkages is synthesized at air-water interface using the Langmuir-Blodgett method. We designed TPE-based monomers with long distances between the TPE and the imine linkages to avoid the charge transfer and therefore keep the fluorescence. A monolayered 2DP provided with more than 104 ?m2 in domain size and around 0.8 nm thickness was obtained through a successive Schiff base reaction at air-water interface. The nanostructures and fluorescent property of 2DP films were characterized by optical microscopy, SEM, TEM, AFM and fluorescence spectrum. Most importantly, the tip-enhanced Raman spectroscopy (TERS) was utilized here to confirm the success of the polycondensation of monolayered 2DP. © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | |
dc.publisher | Wiley-VCH Verlag | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 International | |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Scopus OA2020 | |
dc.subject | 2D polymers | |
dc.subject | aggregation induced emission | |
dc.subject | dynamic chemistry | |
dc.subject | interfacial synthesis | |
dc.subject | supramolecular assembly | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1002/open.202000041 | |
dc.description.sourcetitle | ChemistryOpen | |
dc.description.volume | 9 | |
dc.description.issue | 3 | |
dc.description.page | 381-385 | |
Appears in Collections: | Staff Publications Elements |
Show simple item record
Files in This Item:
File | Description | Size | Format | Access Settings | Version | |
---|---|---|---|---|---|---|
10_1002_open_202000041.pdf | 4.81 MB | Adobe PDF | OPEN | None | View/Download |
This item is licensed under a Creative Commons License